309230
硝酸铊(I)
99.9% trace metals basis
别名:
Thallium mononitrate, Thallous nitrate
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关于此项目
线性分子式:
TlNO3
CAS Number:
分子量:
266.39
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
质量水平
方案
99.9% trace metals basis
表单
solid
solid
反应适用性
core: thallium
杂质
≤1500 mg/kg Trace metallic impurities analysis (ICP)
mp
206 °C (lit.)
SMILES字符串
[Tl+].[O-][N+]([O-])=O
InChI
1S/NO3.Tl/c2-1(3)4;/q-1;+1
InChI key
FYWSTUCDSVYLPV-UHFFFAOYSA-N
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一般描述
硝酸铊为白色结晶，具强氧化性。广泛用于有机合成、分析化学和电子学领域。
应用
硝酸铊用途：
- 作为添加剂，用于电化学沉积法合成含铊的硒化镉薄膜。加入 TlNO3可减轻腐蚀，且有助于形成均匀稳定的薄膜。
- 作为掺杂剂，制备钒酸铋 纳米粒子。TlNO3可减少电荷复合并 增强光催化活性。
- 制备前体溶液，用于 通过分子吸收光谱检测卤素。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Ox. Sol. 3 - STOT RE 2
储存分类代码
5.1B - Oxidizing hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
铊类化学品
危险化学品
Determination of bromine and fluorine via sequential vaporization of TlBr and CaF molecules from the same aliquot by high-resolution continuum source graphite furnace molecular absorption spectrometry
Amauri P.A. Rosa and Tatiane de A. Maranh?o},
Spectrochimica Acta. Part B: Atomic Spectroscopy, 197, 106525-106525 (2022)
Enhanced visible light-photocatalysis by hydrothermally synthesized thallium-doped bismuth vanadate nanoparticles
C.Karunakaran and S.Kalaivani
Materials Science in Semiconductor Processing, 27, 352-361 (2014)
Vânia M T Carneiro et al.
The Journal of organic chemistry, 75(9), 2877-2882 (2010-04-10)
A diastereoselective route to (+)-bakkenolide A is presented from the readily available optically active Wieland-Miescher ketone. This novel synthesis of this sesquiterpene lactone features the following as key stereoselective transformations: (i) the ring contraction reaction of a octalone mediated by
Cecilia Eliana Hanzel et al.
Toxicology and applied pharmacology, 236(1), 59-70 (2009-04-18)
Thallium (Tl) is a highly toxic metal though yet its mechanisms are poorly understood. Previously, we demonstrated that rat pheochromocytoma (PC12) cells exposure to thallous (Tl(I)) or thallic (Tl(III)) cations leads to mitochondrial damage and reduced cell viability. In the
Tl+ increases the permeability of the inner membranes of rat liver mitochondria for monovalent cations.
S M Korotkov et al.
Doklady. Biochemistry and biophysics, 378, 145-149 (2001-11-20)
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