309346
L-谷氨酸二乙酯 盐酸盐
97%
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线性分子式:
C2H5OCOCH2CH2CH(NH2)COOC2H5 · HCl
化学文摘社编号:
分子量:
239.70
UNSPSC Code:
12352209
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-270-4
Beilstein/REAXYS Number:
3597595
MDL number:
InChI key
WSEQLMQNPBNMSL-FJXQXJEOSA-N
InChI
1S/C9H17NO4.ClH/c1-3-13-8(11)6-5-7(10)9(12)14-4-2;/h7H,3-6,10H2,1-2H3;1H/t7-;/m0./s1
SMILES string
Cl[H].CCOC(=O)CC[C@H](N)C(=O)OCC
assay
97%
optical activity
[α]18/D +22°, c = 1 in H2O
reaction suitability
reaction type: solution phase peptide synthesis
mp
108-110 °C (lit.)
application(s)
peptide synthesis
Quality Level
Application
L-Glutamic acid diethyl ester hydrochloride can be used in the synthesis of:
- Oligo(γ-ethyl L-glutamate) via oligomerization catalyzed by papain.
- L-glutamic acid based dendritic compounds.
- Poly(α-peptide) by polymerization and copolymerization in the presence of protease catalysts.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Ultrasound induced formation of organogel from a glutamic dendron
Li Y, et al.
Tetrahedron, 63(31), 7468-7473 (2007)
Rapid regioselective oligomerization of L-glutamic acid diethyl ester catalyzed by papain
Li G, et al.
Macromolecules, 39(23), 7915-7921 (2006)
F Barnabi et al.
American journal of physiology. Regulatory, integrative and comparative physiology, 281(5), R1665-R1674 (2001-10-20)
Neurotransmitters relaying ascending visceral information were examined by comparing the response of neurons in the insular cortex to vagal stimulation (0.8 Hz, 2 mA) before and after neurotransmitter antagonist injections (200 nl) in the ventroposterior parvocellular nucleus of the thalamus
B W Peeters et al.
Brain research bulletin, 33(6), 715-718 (1994-01-01)
The interaction between NMDA and nonNMDA receptors was studied in nonconvulsive epilepsy in WAG/Rij rats. Compounds acting on NMDA (NMDA, APH) and nonNMDA (AMPA, GDEE, kainic acid, kynurenic acid) receptors were coinjected intracerebroventricularly. The WAG/Rij rat strain may be an
K Horie et al.
Life sciences, 57(8), 735-741 (1995-01-01)
Novel vasoconstrictor peptides, endothelin-1 (ET-1) and endothelin-3 (ET-3), are also known as neuropeptides or neuromodulators. When either ET-1 or ET-3 was administered to the rat striatum via a microinjection needle, the dopamine release from the striatum dose-dependently increased. Pretreatment with
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