Merck
CN
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文件

309346

Sigma-Aldrich

L-谷氨酸二乙酯 盐酸盐

97%

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线性分子式:
C2H5OCOCH2CH2CH(NH2)COOC2H5 · HCl
CAS号:
1118-89-4
分子量:
239.70
Beilstein:
3597595
EC 号:
214-270-4
MDL编号:
MFCD00012509
PubChem化学物质编号:
24858729
NACRES:
NA.22

质量水平

200

检测方案

97%

旋光性

[α]18/D +22°, c = 1 in H2O

reaction suitability

reaction type: solution phase peptide synthesis

mp

108-110 °C (lit.)

application(s)

peptide synthesis

SMILES string

Cl[H].CCOC(=O)CC[C@H](N)C(=O)OCC

InChI

1S/C9H17NO4.ClH/c1-3-13-8(11)6-5-7(10)9(12)14-4-2;/h7H,3-6,10H2,1-2H3;1H/t7-;/m0./s1

InChI key

WSEQLMQNPBNMSL-FJXQXJEOSA-N

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相关类别

应用

L-Glutamic acid diethyl ester hydrochloride can be used in the synthesis of:
  • Oligo(γ-ethyl L-glutamate) via oligomerization catalyzed by papain.
  • L-glutamic acid based dendritic compounds.
  • Poly(α-peptide) by polymerization and copolymerization in the presence of protease catalysts.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Ultrasound induced formation of organogel from a glutamic dendron
Li Y, et al.
Tetrahedron, 63(31), 7468-7473 (2007)
Rapid regioselective oligomerization of L-glutamic acid diethyl ester catalyzed by papain
Li G, et al.
Macromolecules, 39(23), 7915-7921 (2006)
Hiroshi Uyama et al.
Biomacromolecules, 3(2), 318-323 (2002-03-13)
Protease-catalyzed polymerization and copolymerization of L-glutamic acid diethyl ester hydrochloride (1) have been performed in a buffer of high concentration. Papain and bromelain showed high catalytic activity toward the polymerization. H-H COSY NMR analysis of the product showed the exclusive
B W Peeters et al.
Brain research bulletin, 33(6), 709-713 (1994-01-01)
The involvement of AMPA and kainate receptors in nonconvulsive epilepsy was studied by intracerebroventricular injections of AMPA, GDEE, kainic acid and kynurenic acid in WAG/Rij rats. The WAG/Rij rat strain is recognized as an animal model for human absence epilepsy.
J Folbergrová
Experimental neurology, 130(2), 344-350 (1994-12-01)
Homocysteine induces seizures in adult, as well as in immature, experimental animals, but the mechanism of its action is still unknown. The aim of the present study was to examine whether homocysteine in immature animals may act via excitatory amino
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