310670
草酰氯 溶液
2.0 M in methylene chloride
别名:
二氯草酸, 草酰二氯, 草酰氯, 草酸氯
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关于此项目
线性分子式:
ClCOCOCl
化学文摘社编号:
分子量:
126.93
UNSPSC Code:
12352106
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1361988
Form:
liquid
InChI
1S/C2Cl2O2/c3-1(5)2(4)6
SMILES string
ClC(=O)C(Cl)=O
InChI key
CTSLXHKWHWQRSH-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: oxidant
concentration
2.0 M in methylene chloride
density
1.335 g/mL at 25 °C
functional group
acyl chloride
Quality Level
Application
草酰氯一般用作二甲基亚砜活化剂 和氯化剂，将羧酸转化为酸性氯化物。
signalword
Danger
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Synthesis and characterization of highly soluble and heat stable new poly (amide-ether) s containing pyridine rings in the main chain.
Banihashemi A and Vakili MR
e-Polymers, 8(1) (2008)
Catalytic syntheses of N-heterocyclic ynones and ynediones by in situ activation of carboxylic acids with oxalyl chloride.
Christina Boersch et al.
Angewandte Chemie (International ed. in English), 50(44), 10448-10452 (2011-09-13)
Oxidation of long-chain and related alcohols to carbonyls by dimethyl sulfoxide" activated" by oxalyl chloride.
Mancuso AJ, et al.
The Journal of Organic Chemistry, 43(12), 2480-2482 (1978)
Benoît Heurtaux et al.
The Journal of organic chemistry, 70(4), 1474-1477 (2005-02-12)
[reaction: see text] Several natural pulvinic acids were synthesized. Silyl ketene acetals derived from methyl arylacetates (4 equiv) reacted with oxalyl chloride at -78 degrees C, without the need of adding a catalyst. After treatment of the crude diketones with
Sham M Sondhi et al.
European journal of medicinal chemistry, 43(12), 2824-2830 (2007-11-21)
A series of substituted N-methylisonicotinamidine (2a-f), N-methylpyrazine-2-carboxamidine (2g-i) derivatives were synthesized by reaction of amidine derivatives (1a-i) with methyl iodide in presence of triethylamine. Five-membered condensed dihydroimidazolylbenzenesulfonamide derivatives (3a-i) were obtained by the reaction of amidine derivatives (1a-i) with acylating
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