310670
草酰氯 溶液
2.0 M in methylene chloride
别名:
二氯草酸, 草酰二氯, 草酰氯, 草酸氯
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关于此项目
线性分子式:
ClCOCOCl
化学文摘社编号:
分子量:
126.93
UNSPSC Code:
12352106
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1361988
Form:
liquid
InChI
1S/C2Cl2O2/c3-1(5)2(4)6
SMILES string
ClC(=O)C(Cl)=O
InChI key
CTSLXHKWHWQRSH-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: oxidant
concentration
2.0 M in methylene chloride
density
1.335 g/mL at 25 °C
functional group
acyl chloride
Quality Level
Application
草酰氯一般用作二甲基亚砜活化剂 和氯化剂，将羧酸转化为酸性氯化物。
signalword
Danger
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Synthesis and characterization of highly soluble and heat stable new poly (amide-ether) s containing pyridine rings in the main chain.
Banihashemi A and Vakili MR
e-Polymers, 8(1) (2008)
Oxidation of long-chain and related alcohols to carbonyls by dimethyl sulfoxide" activated" by oxalyl chloride.
Mancuso AJ, et al.
The Journal of Organic Chemistry, 43(12), 2480-2482 (1978)
Tsutomu Kimura et al.
Chemical communications (Cambridge, England), (32)(32), 4077-4079 (2005-08-11)
Reaction of diastereomerically pure phosphinoselenoic acid salts with oxalyl chloride leads to enantiomerically pure P-chiral phosphinoselenoic chlorides with inversion of configuration at phosphorus; one of these chlorides is converted to a phosphinoselenothioic acid salt with a high degree of enantioselectivity.
Peter J Manley et al.
Organic letters, 4(18), 3127-3129 (2002-08-31)
[reaction: see text] A mild, practical, one-pot method for the generation of imidoyl chlorides and their subsequent in situ reaction with pyridine-1-oxides is described. The imidoyl chlorides were formed from the reaction of secondary amides with a stoichiometric amount of
Taisuke Itaya et al.
Chemical & pharmaceutical bulletin, 50(1), 83-86 (2002-02-05)
The relationship between the product patterns and the configurations of 1,2-cycloheptane- and 1,2-cyclooctanediols 9 in the cyclocondensations with oxalyl chloride in the presence of triethylamine at 0 degrees C has been shown analogous to that obtained for 1,2-disubstituted acyclic ethylene
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