311308
1,4,7-三氮杂环壬烷
95%
别名:
三乙基烯三胺, 八氢-1H-1,4,7-三偶氮宁
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关于此项目
经验公式（希尔记法）:
C6H15N3
化学文摘社编号:
分子量:
129.20
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
773877
Assay:
95%
Form:
solid
InChI
1S/C6H15N3/c1-2-8-5-6-9-4-3-7-1/h7-9H,1-6H2
SMILES string
C1CNCCNCCN1
InChI key
ITWBWJFEJCHKSN-UHFFFAOYSA-N
assay
95%
form
solid
bp
110-130 °C/7 mmHg (lit.)
Quality Level
Application
作为原料用于合成 1,4,7-三官能化衍生物，它们可应用于金属络合领域。
有可能应用于具有高阳离子结合选择性的络合滴定。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Journal of the Chemical Society. Chemical Communications, 1473-1473 (1991)
Didar Asik et al.
Molecules (Basel, Switzerland), 25(10) (2020-05-18)
Complexes of Fe(III) that contain a triazacyclononane (TACN) macrocycle, two pendant hydroxyl groups, and a third ancillary pendant show promise as MRI contrast agents. The ancillary group plays an important role in tuning the solution relaxivity of the Fe(III) complex
Aline Nonat et al.
Inorganic chemistry, 48(9), 4207-4218 (2009-04-08)
The tripodal H(3)thqtcn ligand allows the synthesis of well-defined neutral monomeric syn-tris(hydroxyquinolinate) complexes of lanthanides. Pure [Ln(thqtcn)] complexes (Ln = Nd, 1; Er, 2; Yb, 3) of the triply deprotonated ligand thqtcn(3-) were prepared. Crystallographic characterization was carried out for
Piper J Klemm et al.
Contrast media & molecular imaging, 7(1), 95-99 (2012-02-22)
Commercial gadolinium magnetic resonance imaging (MRI) contrast agents are limited by low relaxivity (r₁) and coordination to only a single water molecule (q = 1). Consequently, gram quantities of these agents must be injected to obtain sufficient diagnostic contrast. In this study
Jun-Fang Guo et al.
Inorganic chemistry, 49(4), 1607-1614 (2010-01-14)
A novel dicyanoosmium(III) complex, trans-Ph(4)P[Os(III)(salen)(CN)(2)].CH(2)Cl(2).H(2)O (1; Ph(4)P(+) = tetraphenylphosphonium cation, salen(2-) = N,N'-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me(3)tacn)(H(2)O)(2)](ClO(4))(2) (Me(3)tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)(2)](2)[Cu(Me(3)tacn)].CH(3)OH (2) and
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