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关于此项目
线性分子式:
(CH3)4N(CH3CO2)3BH
化学文摘社编号:
分子量:
263.10
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8238791
Assay:
95%
Form:
solid
InChI
1S/C6H10BO6.C4H12N/c1-4(8)11-7(12-5(2)9)13-6(3)10;1-5(2,3)4/h7H,1-3H3;1-4H3/q-1;+1
SMILES string
C[N+](C)(C)C.CC(=O)O[BH-](OC(C)=O)OC(C)=O
InChI key
LCFZZOGKVOTFPU-UHFFFAOYSA-N
assay
95%
form
solid
Quality Level
reaction suitability
core: ammonium, reagent type: reductant
mp
93-98 °C (lit.)
functional group
amine
Application
选择性还原剂。
signalword
Danger
hcodes
target_organs
Respiratory system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2
法规信息
新产品
此项目有
Chemtracts, 5, 188-192 (1992)
Ning Shangguan et al.
Organic letters, 9(6), 1093-1096 (2007-02-27)
A formal synthesis of psymberin (irciniastatin A) is presented. Notable features of the synthesis include the chemo-, regio-, and stereoselective oxidation of a 1,3-disubstituted allene, a configuration-dependent spirodiepoxide opening, the efficient syntheses of functionalized trans-2,6-disubstituted pyrans, and the union of
Tetrahedron Letters, 44, 7239-7243 (2003)
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