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Merck
CN

317594

三甲胺N-氧化物

95%

别名:

TMANO

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关于此项目

线性分子式:
(CH3)3N(O)
化学文摘社编号:
分子量:
75.11
EC 号:
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

95%

反应适用性

reagent type: oxidant

mp

220-222 °C (lit.)

官能团

amine

SMILES字符串

C[N+](C)(C)[O-]

InChI

1S/C3H9NO/c1-4(2,3)5/h1-3H3

InChI key

UYPYRKYUKCHHIB-UHFFFAOYSA-N

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一般描述

三甲胺N-氧化物是一种有机化合物,属于氧化胺类。它通常存在于海洋生物的组织中,可以帮助保护它们免受盐碱、静水压力、温度和高尿素等恶劣条件的侵害。

应用

三甲胺N-氧化物可用于:
  • 用作有机金属化合物的脱金属和脱羰试剂
  • 与二异丙基氨基锂反应制备甲亚胺叶立德。进而与简单的烯烃反应制得相应的吡咯烷。
  • 介导硫醇到二硫化物的转化。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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EBioMedicine, 44, 502-515 (2019-05-13)
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Hydride ion transfer from carbon-hydrogen bonds to carbon disulfide, carbonyl sulfide, and carbon dioxide. Synthesis, reactivity, and structure of manganese complexes (η 5-C6MenH7-n) Mn (CO) LL'
Snyder DB, et al.
Journal of the American Chemical Society, 115(15), 6718-6729 (1993)
Trimethylamine N-oxide as a precursor of azomethine ylides
Beugelmans R, et al.
Journal of the Chemical Society. Chemical Communications, 471(1), 31-32 (1983)
J Klysik et al.
FEBS letters, 333(3), 261-267 (1993-11-01)
The ability of the Escherichia coli single-stranded DNA-binding protein (SSB) to recognize structural features associated with intramolecular triplex formation in oligopurine.oligopyrimidine (pur.pyr) inserts in recombinant plasmids was evaluated. The SSB protein binds to supercoiled plasmids and causes a site-preferential increase

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