318183
硫酸甲酯 钠盐
别名:
甲基硫酸钠
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关于此项目
线性分子式:
CH3OSO3Na
化学文摘社编号:
分子量:
134.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
208-142-7
MDL number:
Form:
powder
InChI key
DZXBHDRHRFLQCJ-UHFFFAOYSA-M
InChI
1S/CH4O4S.Na/c1-5-6(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
SMILES string
[Na+].COS([O-])(=O)=O
form
powder
impurities
<3% methanol, <5% water
mp
210 °C (lit.)
Quality Level
Application
参与的反应物或试剂：
- 微乳液法制备混杂纳米材料片层结构的研究
- 离子液体辐射分解产生自由基离子的 EPR 研究
- 微细胞研究特别是 1-苯甲酰基-1,2,4-三唑类化合物的水解缓速作用和混合胶束的自组装/微结构
硫酸甲酯钠盐可用于合成：
- 基于硫酸甲酯阴离子的1,3,4-三烷基-1,2,3-三唑离子液体，用于Morita–Baylis–Hillman反应。
- 与酚反应合成苯甲醚。
- 羟基苯胺喹啉类化合物，用作RET激酶抑制剂。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis of anisole from phenol and sodium methyl sulfate, a byproduct from synthesis of medicine intermediates
Guoping W, et al.
Petrochemical Technology, 45(11), 1337-1337 (2016)
The discovery of substituted 4-(3-hydroxyanilino)-quinolines as potent RET kinase inhibitors
Robinett R G, et al.
Bioorganic & Medicinal Chemistry Letters, 17(21), 5886-5893 (2007)
V Chatsudthipong et al.
The Journal of pharmacology and experimental therapeutics, 288(3), 993-1001 (1999-02-23)
The transport step for p-aminohippurate (PAH) from cell to lumen across the luminal membrane of rabbit proximal tubules has not been adequately defined. To examine this process more closely, we determined the effects of possible transport inhibitors and substitutes for
Catherine Cook Kaczorowski et al.
The Journal of physiology, 578(Pt 3), 799-818 (2006-12-02)
CA1 pyramidal neurons from animals that have acquired hippocampal tasks show increased neuronal excitability, as evidenced by a reduction in the postburst afterhyperpolarization (AHP). Studies of AHP plasticity require stable long-term recordings, which are affected by the intracellular solutions potassium
M A Sallam et al.
Carbohydrate research, 330(1), 53-63 (2001-02-24)
Dehydration of 4-(D-galacto-pentitol-1-yl)-2-phenyl-2H-1,2,3-triazole with 20% methanolic sulfuric acid afforded the anomeric pairs of nucleosides, 4-(alpha-D-lyxopyranosyl)-2-phenyl-2H-1,2,3-triazole (major component) and its beta-anomer, as well as 4-(alpha-D-lyxofuranosyl)-2H-1,2,3-triazole and its beta-anomer. The four anomeric C-nucleosides were separated by chromatography, and their structure and anomeric
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