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Merck
CN

318183

硫酸甲酯 钠盐

别名:

甲基硫酸钠

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关于此项目

线性分子式:
CH3OSO3Na
化学文摘社编号:
分子量:
134.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
208-142-7
MDL number:
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InChI key

DZXBHDRHRFLQCJ-UHFFFAOYSA-M

InChI

1S/CH4O4S.Na/c1-5-6(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

SMILES string

[Na+].COS([O-])(=O)=O

form

powder

impurities

<3% methanol
<5% water

mp

210 °C (lit.)

Quality Level

Application

参与的反应物或试剂:
  • 微乳液法制备混杂纳米材料片层结构的研究
  • 离子液体辐射分解产生自由基离子的 EPR 研究
  • 微细胞研究特别是 1-苯甲酰基-1,2,4-三唑类化合物的水解缓速作用和混合胶束的自组装/微结构
硫酸甲酯钠盐可用于合成:
  • 基于硫酸甲酯阴离子的1,3,4-三烷基-1,2,3-三唑离子液体,用于Morita–Baylis–Hillman反应。
  • 与酚反应合成苯甲醚。
  • 羟基苯胺喹啉类化合物,用作RET激酶抑制剂。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of anisole from phenol and sodium methyl sulfate, a byproduct from synthesis of medicine intermediates
Guoping W, et al.
Petrochemical Technology, 45(11), 1337-1337 (2016)
Synthesis of new triazolium-based ionic liquids and their use in the Morita-Baylis-Hillman reaction
F Alioune, et al.
Tetrahedron Letters, 56(36), 5128-5131 (2015)
The discovery of substituted 4-(3-hydroxyanilino)-quinolines as potent RET kinase inhibitors
Robinett R G, et al.
Bioorganic & Medicinal Chemistry Letters, 17(21), 5886-5893 (2007)
Catherine Cook Kaczorowski et al.
The Journal of physiology, 578(Pt 3), 799-818 (2006-12-02)
CA1 pyramidal neurons from animals that have acquired hippocampal tasks show increased neuronal excitability, as evidenced by a reduction in the postburst afterhyperpolarization (AHP). Studies of AHP plasticity require stable long-term recordings, which are affected by the intracellular solutions potassium
M A Sallam et al.
Carbohydrate research, 330(1), 53-63 (2001-02-24)
Dehydration of 4-(D-galacto-pentitol-1-yl)-2-phenyl-2H-1,2,3-triazole with 20% methanolic sulfuric acid afforded the anomeric pairs of nucleosides, 4-(alpha-D-lyxopyranosyl)-2-phenyl-2H-1,2,3-triazole (major component) and its beta-anomer, as well as 4-(alpha-D-lyxofuranosyl)-2H-1,2,3-triazole and its beta-anomer. The four anomeric C-nucleosides were separated by chromatography, and their structure and anomeric

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