318183
硫酸甲酯 钠盐
别名:
甲基硫酸钠
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关于此项目
线性分子式:
CH3OSO3Na
化学文摘社编号:
分子量:
134.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
208-142-7
MDL number:
Form:
powder
InChI key
DZXBHDRHRFLQCJ-UHFFFAOYSA-M
InChI
1S/CH4O4S.Na/c1-5-6(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1
SMILES string
[Na+].COS([O-])(=O)=O
form
powder
impurities
<3% methanol, <5% water
mp
210 °C (lit.)
Quality Level
Application
参与的反应物或试剂：
- 微乳液法制备混杂纳米材料片层结构的研究
- 离子液体辐射分解产生自由基离子的 EPR 研究
- 微细胞研究特别是 1-苯甲酰基-1,2,4-三唑类化合物的水解缓速作用和混合胶束的自组装/微结构
硫酸甲酯钠盐可用于合成：
- 基于硫酸甲酯阴离子的1,3,4-三烷基-1,2,3-三唑离子液体，用于Morita–Baylis–Hillman反应。
- 与酚反应合成苯甲醚。
- 羟基苯胺喹啉类化合物，用作RET激酶抑制剂。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synthesis of new triazolium-based ionic liquids and their use in the Morita-Baylis-Hillman reaction
F Alioune, et al.
Tetrahedron Letters, 56(36), 5128-5131 (2015)
Synthesis of anisole from phenol and sodium methyl sulfate, a byproduct from synthesis of medicine intermediates
Guoping W, et al.
Petrochemical Technology, 45(11), 1337-1337 (2016)
The discovery of substituted 4-(3-hydroxyanilino)-quinolines as potent RET kinase inhibitors
Robinett R G, et al.
Bioorganic & Medicinal Chemistry Letters, 17(21), 5886-5893 (2007)
Jesús Oria-Hernández et al.
The Journal of biological chemistry, 280(45), 37924-37929 (2005-09-09)
For more than 50 years, it has been known that K(+) is an essential activator of pyruvate kinase (Kachmar, J. F., and Boyer, P. D. (1953) J. Biol. Chem. 200, 669-683). However, the role of K(+) in the catalysis by
Beatriz Abad-Romero et al.
Carbohydrate research, 344(1), 21-28 (2008-11-11)
Methyl xylobioside and methyl xylotrioside were prepared from the peracetylated anomeric xylosyl trichloroacetimidates by reaction with methanol followed by Zemplén deacetylation. Methyl beta-D-xylopyranoside, methyl beta-D-xylobioside and methyl beta-D-xylotrioside were subjected to treatment with dibutyltin oxide followed by reaction with the
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