319813
氰基甲酸甲酯
99%
别名:
2-甲氧基-2-氧代乙腈, [(氰羰基)氧基]甲烷, 曼德氏试剂, 氰甲酸甲酯, 碳酸甲酯
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关于此项目
线性分子式:
NCCO2CH3
化学文摘社编号:
分子量:
85.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-626-6
Beilstein/REAXYS Number:
1742994
MDL number:
Assay:
99%
Form:
liquid
产品名称
氰基甲酸甲酯, 99%
InChI key
OBWFJXLKRAFEDI-UHFFFAOYSA-N
InChI
1S/C3H3NO2/c1-6-3(5)2-4/h1H3
SMILES string
COC(=O)C#N
assay
99%
form
liquid
refractive index
n20/D 1.374 (lit.)
bp
100-101 °C (lit.)
density
1.072 g/mL at 25 °C (lit.)
functional group
ester
nitrile
Quality Level
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Application
选择性酰化试剂。
General description
氰甲酸甲酯是一种有机化合物，通常用作有机合成中的甲氧羰基源。它最常见的用途是作为反应物通过烯醇锂的碳酰化合成区域选择性β-酮酯。相比于更为传统的试剂，如酰基卤、酐和二氧化碳，它是一种更优良的酰化剂。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
78.8 °F - closed cup
flash_point_c
26 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
非剧毒-急性毒性1
此项目有
Aldrichimica Acta, 20, 53-53 (1987)
Tetrahedron Letters, 34, 8553-8553 (1993)
Tetrahedron, 48, 7979-7979 (1992)
D L Selwood et al.
Journal of medicinal chemistry, 36(23), 3503-3510 (1993-11-12)
A variety of isosteres of the DNA polymerase inhibitor aphidicolin were synthesized as potential antiherpes agents. Modeling studies indicated that the bicyclooctane C, D rings of aphidicolin could be replaced by an aromatic moiety while maintaining the spatial arrangement of
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