grade
synthesis grade
vapor density
4.9 (vs air)
vapor pressure
4.2 mmHg ( 20 °C)
expl. lim.
36 %
reaction suitability
core: boron, reagent type: Lewis acid, reagent type: catalyst
concentration
≥46% boron trifluoride
refractive index
n20/D 1.344 (lit.)
bp
126-129 °C (lit.)
mp
−58 °C (lit.)
density
1.15 g/mL (lit.)
format
neat
storage temp.
2-8°C
SMILES string
CC[O+](CC)[B-](F)(F)F
InChI
1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3
InChI key
MZTVMRUDEFSYGQ-UHFFFAOYSA-N
Other Notes
This product has been replaced by 175501-ALDRICH | Boron trifluoride diethyl etherate for synthesis
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation
target_organs
Kidney
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
137.3 °F - closed cup
flash_point_c
58.5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
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M S F Lie Ken Jie et al.
Chemistry and physics of lipids, 125(2), 93-101 (2003-09-23)
Methyl santalbate (methyl trans-11-octadecen-9-ynoate) from Sandal wood seed oil, Santalbum alum) was epoxidized to methyl trans-11,12-epoxy-octadec-9-ynoate (1). Treatment of compound 1 with tetrabutylammonium dihydrogentrifluoride, and boron trifluoride etherate gave the corresponding anti- (2a) (57%) and syn- (2b) (35%) fluorohydrin derivatives
George R Pettit et al.
Journal of natural products, 74(9), 1922-1930 (2011-09-09)
The synthesis of bis-steroidal pyrazines derived from 3-oxo-11,21-dihydroxypregna-4,17(20)-diene (4) and glycosylation of a D-ring side chain with α-L-rhamnose have been summarized. Rearrangement of steroidal pyrazine 10 to 14 was found to occur with boron triflouride etherate. Glycosylation of pyrazine 10
Kevin M McQuaid et al.
Journal of the American Chemical Society, 131(2), 402-403 (2008-12-23)
C-H bond functionalization enables strategically new approaches to the synthesis of complex organic molecules including biologically active compounds, research probes and functional organic materials. To address the shortcomings of transition metal catalyzed processes, we have developed a new approach to