320323
1-己烯
97%
别名:
1-n-Hexene
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关于此项目
线性分子式:
CH3(CH2)3CH=CH2
化学文摘社编号:
分子量:
84.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-753-1
Beilstein/REAXYS Number:
1209240
MDL number:
Assay:
97%
Form:
liquid
InChI key
LIKMAJRDDDTEIG-UHFFFAOYSA-N
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
SMILES string
CCCCC=C
vapor density
3 (vs air)
vapor pressure
155 mmHg ( 21.1 °C)
assay
97%
form
liquid
autoignition temp.
487 °F
Quality Level
bp
60-66 °C (lit.)
density
0.678 g/mL at 25 °C (lit.)
functional group
allyl
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Application
1-己烯可用于以下情形：
- 配合各种催化剂作为聚合反应底物。
- 采用低聚法制备优质中馏分和润滑油。
- 使用超临界CO2和铑系催化剂，通过氢甲酰化反应合成醛类。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
supp_hazards
存储类别
3 - Flammable liquids
flash_point_f
-13.0 °F - closed cup
flash_point_c
-25.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Oligomerization of 1-hexene and 1-octene over solid acid catalysts.
de Klerk A.
Industrial & Engineering Chemistry Research, 44(11), 3887-3893 (2005)
Hydroformylation of 1-hexene in supercritical carbon dioxide using a heterogeneous rhodium catalyst. 3. Evaluation of solvent effects.
Hemminger O, et al.
Green Chemistry, 4(5), 507-512 (2002)
Isospecific living polymerization of 1-hexene by a readily available nonmetallocene C 2-symmetrical zirconium catalyst.
Tshuva, Edit Y et al.
Journal of the American Chemical Society, 122(43), 10706-10707 (2000)
Stereospecific living Ziegler- Natta polymerization of 1-hexene.
Jayaratne, Kumudini C and Sita, Lawrence R
Journal of the American Chemical Society, 122(5), 958-959 (2000)
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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