产品名称
三甲基膦 溶液, 1.0 M in THF
form
liquid
Quality Level
reaction suitability
reagent type: ligand
reaction type: Mitsunobu Reaction, reagent type: ligand
reaction type: Wittig Reaction
concentration
1.0 M in THF
density
0.872 g/mL at 25 °C
functional group
phosphine
SMILES string
CP(C)C
InChI
1S/C3H9P/c1-4(2)3/h1-3H3
InChI key
YWWDBCBWQNCYNR-UHFFFAOYSA-N
General description
三甲基膦是用于 Mitsunobu 反应的试剂。参与叠氮化物转化为氨基甲酸酯类、叠氮醇转化的氮杂环丙烷类、亚氨基磷烷类和氮杂-Wittig 反应。三甲基膦的电子衍射研究已有报道。
Application
三甲基膦 (PMe 3 ) 溶液是合成 Fe/Te 簇合物类型 e 6 Te 8 (PMe 3 ) 6 中使用的合适试剂。它可以用作 Y 型分子筛酸中心的探针。可用于合成六（三甲基膦）三-μ-亚甲基二钌 (III)。
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-22.0 °F - closed cup
flash_point_c
-30 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
相关内容
Phosphine Ligand Application Guide
Acid sites in zeolite Y: a solid-state NMR and infrared study using trimethylphosphine as a probe molecule.
Lunsford JH, et al.
Journal of the American Chemical Society, 107(6), 1540-1547 (1985)
Electron diffraction study of the structure of trimethylphosphine.
Bartell LS and Brockway LO.
J. Chem. Phys. , 32(2), 512-515 (1960)
Synthesis and x-ray crystal structures of hexakis (trimethylphosphine) tris-. mu.-methylene-diruthenium (III) and its mono-and dicationic derivatives.
Hursthouse MB, et al.
Journal of the American Chemical Society, 101(15), 4128-4139 (1979)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 324108-100ML | 04061826709825 |