方案
99%
旋光性
[α]19/D −21°, c = 4 in H2O
mp
248-251 °C (lit.)
储存温度
−20°C
SMILES字符串
OC[C@H]1O[C@@H]2[C@@H](OC3=NC(=O)C=C[N@@H]23)[C@@H]1O
InChI
1S/C9H10N2O5/c12-3-4-6(14)7-8(15-4)11-2-1-5(13)10-9(11)16-7/h1-2,4,6-8,12,14H,3H2/t4-,6-,7+,8-/m1/s1
InChI key
UUGITDASWNOAGG-CCXZUQQUSA-N
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应用
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储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
A K Drabikowska et al.
Biochemical pharmacology, 36(23), 4125-4128 (1987-12-01)
Two series of 5-substituted uracil N(1)-acyclonucleosides, each with a different acyclic chain, were examined as inhibitors of uridine phosphorylase from rat intestinal mucosa, and several against the enzyme from Ehrlich ascites cells. In addition, several 5-substituted analogues of 2,2'-anhydrouridine were
Christopher S Theile et al.
Chemical communications (Cambridge, England), 48(45), 5587-5589 (2012-04-26)
Here we present new routes for the efficient syntheses of 6,5'-(S)- and 6,5'-(R)-cyclouridine. The syntheses utilize readily accessible uridine as a starting material. This route to the R diastereomer is significantly more efficient than previous synthetic efforts, allowing us to
Vladimir I Timofeev et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 63(Pt 10), 852-854 (2007-10-03)
Uridine phosphorylase (UPh; EC 2.4.2.3) is a member of the pyrimidine nucleoside phosphorylase family of enzymes which catalyzes the phosphorolytic cleavage of the C-N glycoside bond of uridine, with the formation of ribose 1-phosphate and uracil. This enzyme has been
Ying Fu et al.
Acta crystallographica. Section C, Crystal structure communications, 69(Pt 3), 282-284 (2013-03-06)
2,2'-Anhydro-1-(3',5'-di-O-acetyl-β-D-arabinofuranosyl)uracil, C13H14N2O7, was obtained by refluxing 2',3'-O-(methoxymethylene)uridine in acetic anhydride. The structure exhibits a nearly perfect C4'-endo ((4)E) conformation. The best four-atom plane of the five-membered furanose ring is O-C-C-C, involving the C atoms of the fused five-membered oxazolidine ring
Aldrichimica Acta, 20, 52-52 (1987)
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