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324450

(S)-(+)-1-(2-吡咯烷甲基)吡咯烷

Name: (<I>S</I>)-(+)-1-(2-吡咯烷甲基)吡咯烷
Brand: ALDRICH

96%

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关于此项目

经验公式（希尔记法）:

C₉H₁₈N₂

化学文摘社编号:

51207-66-0

分子量:

154.25

NACRES:

NA.22

PubChem Substance ID:

24859441

UNSPSC Code:

12352005

MDL number:

MFCD00013441

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属性

Quality Level

100

assay

96%

optical activity

[α]19/D +7.0°, c = 2.4 in ethanol

refractive index

n20/D 1.4871 (lit.)

bp

99-101 °C/2 mmHg (lit.)

density

0.946 g/mL at 25 °C (lit.)

SMILES string

C1CCN(C1)C[C@@H]2CCCN2

InChI

1S/C9H18N2/c1-2-7-11(6-1)8-9-4-3-5-10-9/h9-10H,1-8H2/t9-/m0/s1

InChI key

YLBWRMSQRFEIEB-VIFPVBQESA-N

说明

Application

(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine can be used as an organocatalyst in the asymmetric synthesis of different optically active organic building blocks via Aldol condensation and Mannich reactions . It is also used as a catalyst to prepare enantioselective Michael adducts by reacting alkylidene malonates with unactivated ketones.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

0000461507

0000232154

0000207583

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商品

Chiral Vicinal Diamines for Asymmetric Synthesis

Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.

(S)-(+)-1-(2-pyrrolidinylmethyl)pyrrolidine ? an effective catalyst of asymmetric synthesis

VM Tkachuk, et al.

Zhurnal Organichnoi ta Farmatsevtichnoi Khimii, 3-16 (2014)

The murine orthologue of the Golgi-localized TPTE protein provides clues to the evolutionary history of the human TPTE gene family.

M Guipponi et al.

Human genetics, 109(6), 569-575 (2002-01-26)

The human TPTE gene encodes a testis-specific protein that contains four potential transmembrane domains and a protein tyrosine phosphatase motif, and shows homology to the tumor suppressor PTEN/MMAC1. Chromosomal mapping revealed multiple copies of the TPTE gene present on the

Catalytic enantioselective direct Michael additions of ketones to alkylidene malonates

Betancort JM, et al.

Tetrahedron Letters, 42(27), 4441-4444 (2001)

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货号	GTIN
324450-1G	04061838097699
324450-250MG	04061838126511