324647
烯丙基硼酸频哪醇酯
97%
别名:
2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷, 丙烯基硼酸频哪醇酯
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关于此项目
线性分子式:
((CH3)4C2O2)BCH2CH=CH2
化学文摘社编号:
分子量:
168.04
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
烯丙基硼酸频哪醇酯, 97%
InChI
1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3
SMILES string
CC1(C)OB(CC=C)OC1(C)C
InChI key
YMHIEPNFCBNQQU-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.4268 (lit.)
bp
50-53 °C/5 mmHg (lit.)
density
0.896 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
作为试剂用于以下反应
试剂用于制备
- 钯催化的铃木宫村交叉偶联反应和烯烃复分解
- 分子间自由基加成
- 手性螺二茚二醇（SPINOL）基磷酸催化醛烯丙基化
- 钴催化二烯与烯烃的区域选择性加氢乙烯基化
- 核酸模板能量转移导致光释放反应
- 立体选择性铟催化的Hosomi-Sakurai反应
试剂用于制备
- 环砜羟乙胺作为BACE1抑制剂减少淀粉样蛋白β-肽
- 碳烯碘化钌与银羧酸盐的金属转移，得到碳氢活化的钌碳烯配合物作为Z选择性烯烃复分解的催化剂
- 烯丙基硼化试剂，用于制备烯丙醇和高烯丙基胺。
General description
烯丙基硼酸季戊醇酯在简单酮亚胺的催化烯丙基化反应中被用作亲核试剂。
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
114.8 °F - closed cup
flash_point_c
46 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A catalytic asymmetric borono variant of Hosomi-Sakurai reactions with N,O-aminals.
Yi-Yong Huang et al.
Angewandte Chemie (International ed. in English), 50(47), 11121-11124 (2011-10-07)
Asymmetric Allylboration of Aldehydes with Pinacol Allylboronates Catalyzed by 1,1'-Spirobiindane-7,7'-diol (SPINOL) Based Phosphoric Acids
Xing, C-H.; et al.
European Journal of Organic Chemistry, 6, 1115-1118 (2012)
Gaining absolute control of the regiochemistry in the cobalt-catalyzed 1,4-hydrovinylation reaction.
Marion Arndt et al.
Organic letters, 13(23), 6236-6239 (2011-11-02)
The absolute control of the regiochemistry of a cobalt-catalyzed 1,4-hydrovinylation reaction is achieved by alternation of the ligands applied. While the dppe/dppp ligands led to the formation of the branched product, the herein described application of the SchmalzPhos ligand generates
Organometallics, 2, 230-230 (1983)
Catalytic enantioselective allylation of ketoimines
Reiko W et al.
Journal of the American Chemical Society, 128, 7687-7691 (2006)
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