325104
3-硝基苯硼酸
≥97%
别名:
间硝基苯硼酸
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关于此项目
线性分子式:
O2NC6H4B(OH)2
化学文摘社编号:
分子量:
166.93
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2938638
产品名称
3-硝基苯硼酸, ≥97%
InChI
1S/C6H6BNO4/c9-7(10)5-2-1-3-6(4-5)8(11)12/h1-4,9-10H
SMILES string
OB(O)c1cccc(c1)[N+]([O-])=O
InChI key
ZNRGSYUVFVNSAW-UHFFFAOYSA-N
assay
≥97%
form
powder
mp
284-285 °C (dec.) (lit.)
functional group
nitro
Quality Level
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Application
催化炔二羰基化合物的烯碳环化反应
Reactant involved in:
Additionally used as a reactant for synthesizing biologically active molecules such as:
- Copper-catalyzed arylation
- Palladium-catalyzed decarboxylative coupling
- Suzuki-Miyaura cross-coupling
- Oxidative carbocyclization / arylation
- Addition to arylpropargyl alcohols
Additionally used as a reactant for synthesizing biologically active molecules such as:
- Inhibitors of angiogenesis
- Biaryl-olefins with antiproliferative activities
Other Notes
含不定量的酸酐
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Fan Fei et al.
Analytical and bioanalytical chemistry, 398(3), 1349-1356 (2010-07-29)
The design of boronic acid sensors for photometric detection of carbohydrates has relied on exploiting differences in the thermodynamic stability of complex formation for molecular recognition. Herein, we introduce a direct method for analysis of sugar alcohols using 3-nitrophenylboronic acid
Aminophenyl- and nitrophenyl-labeled nucleoside triphosphates: synthesis, enzymatic incorporation, and electrochemical detection.
Hana Cahová et al.
Angewandte Chemie (International ed. in English), 47(11), 2059-2062 (2008-02-09)
C W Garner et al.
Biochimica et biophysica acta, 790(1), 91-93 (1984-10-09)
Horse serum cholinesterase (acylcholine acylhydrolase, EC 3.1.1.8) was reversibly inhibited by a variety of alkyl- and areneboronic acids with Ki values ranging from 6.2 mM (methaneboronic acid) to 3.1 microM (diphenylboric acid). Binding to the enzyme was apparently at the
Malcolm P Nicholls et al.
Organic & biomolecular chemistry, 2(10), 1434-1441 (2004-05-12)
The structures of thermodynamically stable aromatic boronic acid : cyclic carbohydrate chelates in aqueous alkaline media have been studied using 1H NMR spectroscopy and molecular modelling. It is found that interacting saccharides must necessarily possess a synperiplanar diol functionality for
Claire Kaiser et al.
Chemical communications (Cambridge, England), (3)(3), 338-340 (2008-04-11)
Electrokinetic probes based on the differential migration of ternary boronate ester complexes permit the selective analysis of micromolar levels of UV-transparent polyol stereoisomers in urine samples via dynamic complexation-capillary electrophoresis that is applicable to single-step screening of in-born errors of
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