326178
2-乙酰氧基异丁酰氯
95%
别名:
2-乙酰氧基异丁酰氯, 2-乙酸基-2-甲基丙酰氯
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关于此项目
线性分子式:
(CH3)2C(OCOCH3)COCl
化学文摘社编号:
分子量:
164.59
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
255-016-2
Beilstein/REAXYS Number:
507772
MDL number:
产品名称
2-乙酰氧基异丁酰氯, 95%
InChI key
RBTCRFLJLUNCLL-UHFFFAOYSA-N
InChI
1S/C6H9ClO3/c1-4(8)10-6(2,3)5(7)9/h1-3H3
SMILES string
CC(=O)OC(C)(C)C(Cl)=O
assay
95%
form
liquid
refractive index
n20/D 1.428 (lit.)
bp
55-56 °C/6 mmHg (lit.)
density
1.136 g/mL at 25 °C (lit.)
functional group
acyl chloride
ester
Quality Level
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Application
1-Chlorocarbonyl-1-methylethyl acetate was used in preparation of α,γ-dichloro alditols.
General description
Reaction of 1-chlorocarbonyl-1-methylethyl acetate with 1-aryl ethylene glycols to yield trans chlorohydrin acetates was reported.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
154.4 °F - closed cup
flash_point_c
68 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Efficient synthesis of some dichloroalditols: direct regioselective chlorination of some unprotected alditols by 1-chlorocarbonyl-1-methylethyl acetate.
Benazza M, et al.
Journal of Carbohydrate Chemistry, 13(7), 967-979 (1994)
Mahesh K Lakshman et al.
Journal of the American Chemical Society, 129(1), 68-76 (2007-01-04)
A diastereoselective synthesis of the nucleoside adducts corresponding to a cis ring-opening of the carcinogen (+/-)-7 beta, 8 alpha-dihydroxy-9 alpha,10 alpha-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (BaP DE-2) by 2'-deoxyadenosine and 2'-deoxyguanosine is described. The key intermediate (+/-)-10alpha-amino-7beta,8alpha,9alpha-trihydroxy-7,8,9,10-tetrahydrobenzo[a]pyrene was synthesized by a highly diastereoselective dihydroxylation
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