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Merck
CN

32851

反-1,4-二氨基环己烷

≥98.0% (GC)

别名:

反式-1,4-环己二胺

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线性分子式:
C6H10(NH2)2
化学文摘社编号:
分子量:
114.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2801657
Assay:
≥98.0% (GC)
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InChI

1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-

SMILES string

N[C@H]1CC[C@H](N)CC1

InChI key

VKIRRGRTJUUZHS-IZLXSQMJSA-N

vapor pressure

18 mmHg ( 87.2 °C)

assay

≥98.0% (GC)

autoignition temp.

680 °F

expl. lim.

6 %

bp

197 °C (lit.)

mp

68-72 °C (lit.)

Application

反式-1,4-二氨基环己烷可用于制备全脂族聚酰亚胺。 它被用作新型二维层状磷酸锌合成中的结构导向剂。

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 2

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Mohammad S Ali et al.
Journal of inorganic biochemistry, 96(4), 452-456 (2003-09-19)
A series of new platinum(II) and platinum(IV) adducts of type [P(II)(cis-1,4-DACH)LCl]NO(3,) where cis-1,4-DACH=cis-1,4-diaminocyclohexane, and L=9-ethylguanine, 1-methylcytosine, adenine, adenosine, cytosine, cytidine, guanine, and [Pt(IV)(cis-1,4-DACH)Ltrans-(X)(2)Cl]NO(3), (where Y=hydroxo or acetato), were synthesized and characterized by elemental analysis, infrared spectroscopy, and 1H and 195Pt
Han Wang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(42), e2003098-e2003098 (2020-10-01)
The crystalline orientation and phase distribution are two important parameters for high-performance 2D perovskite solar cells. Therefore, it is essential to understand how the structure of spacer ligands influences the orientation and phase distribution of resulting 2D perovskite films. In
Shalini Balakrishnan et al.
The Journal of organic chemistry, 72(25), 9834-9837 (2007-11-06)
To introduce chirality and functional groups adjacent to guanidiniums to modulate specificity and affinity in recognition, N,N'-bis(Boc)-alpha-guanidino acids were synthesized from alpha-amino acid methyl esters. Protected alpha-guanidino acids coupled to cyclohexylamine and trans-1,4-diaminocyclohexane in good yield and with retention of
Hwan-Chul Yu et al.
Journal of nanoscience and nanotechnology, 11(7), 6141-6147 (2011-11-30)
Fully aliphatic polyimides (APIs) were prepared from rel-(1'R,3S5'S)-spiro[furan-3(2H),6'-[3]oxabicyclo[3.2.1]octane]-2,2',4',5(4H)-tetrone (DAn) as unsymmetrical spiro dianhydride, and either cis-trans-1,4-diaminocyclohexane (mix-DACH) or trans-1,4-diaminocyclohexane (trans-DACH) as diamine. Structure of all prepared monomers and polymers was confirmed via 1H-NMR and FT-IR. The solubility, optical transparency, and
F Vianello et al.
Protein expression and purification, 15(2), 196-201 (1999-03-02)
A novel, simple, and rapid procedure for the purification of pea seedling amine oxidase is reported. The crude enzyme, obtained by ammonium sulfate fractionation, was purified in two steps: the first one by anion-exchange chromatography and the second one by

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