328987
氯代二硫代甲酸苯基酯
95%
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线性分子式:
ClCS2C6H5
化学文摘社编号:
分子量:
188.70
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
liquid
InChI
1S/C7H5ClS2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H
SMILES string
ClC(=S)Sc1ccccc1
InChI key
XEXIHCWFFNGQDE-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.6688 (lit.)
bp
135 °C/15 mmHg (lit.)
density
1.331 g/mL at 25 °C (lit.)
functional group
chloro, thioether
storage temp.
2-8°C
Quality Level
General description
已有报道描述了氯代二硫代甲酸苯基酯的溶剂分解反应的动力学和机理。
Application
氯代二硫代甲酸苯基酯可用于合成苯基芳基磺酰基-烷基-二硫代氨基甲酸酯。氯代二硫代甲酸苯基酯还可用于合成 S-苯基- O-(4-硝基苯基)二硫代碳酸酯。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
The nucleofuge in the pyridinolysis of O-(4-nitrophenyl) S-aryl thio and dithiocarbonates.
Castro EA, et al.
Journal of Physical Organic Chemistry, 25(11), 994-994 (2012)
Kinetics and mechanism of the reactions of aryl chlorodithioformates with pyridines and secondary alicyclic amines.
Castro EA, et al.
Journal of Physical Organic Chemistry, 22(11), 1030-1037 (2009)
Synthesis of Phenyl Arylsulfonyl-alkyl-dithiocarbamates and Their Hydrolytic Reactivity in Hydroxide and Hydroperoxide Media.
Norberto F, et al.
European Journal of Organic Chemistry, 2005(21), 4710-4714 (2005)
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