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Merck
CN

32950

4,4′-二氨基二苯甲烷

≥97.0% (GC)

别名:

4,4′-亚甲基双苯胺, MDA

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关于此项目

经验公式(希尔记法):
C13H14N2
化学文摘社编号:
分子量:
198.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-974-4
Beilstein/REAXYS Number:
474706
MDL number:
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产品名称

4,4′-二氨基二苯甲烷, ≥97.0% (GC)

Quality Level

InChI key

YBRVSVVVWCFQMG-UHFFFAOYSA-N

InChI

1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2

SMILES string

Nc1ccc(Cc2ccc(N)cc2)cc1

assay

≥97.0% (GC)

mp

88-92 °C

solubility

water: soluble

Gene Information

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Application

4,4′-二氨基二苯甲烷已被用于:
  • 作为双酚印迹的虚拟模板
  • 氨基修饰的多壁碳纳米管/聚二甲基硅氧烷的合成
  • 作为固化剂以研究环氧树脂复合材料的形成动力学
  • 在橡胶工业中用作环氧树脂硬化剂

General description

4,4′-二氨基二苯基甲烷作为双齿桥联配体,与其胺的氢原子形成氢键,并且参与多种非共价相互作用。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1

target_organs

Liver, Liver,eye - retina

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

429.8 °F - closed cup

flash_point_c

221 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品
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分析证书(COA)

Lot/Batch Number

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Six transition metal--organic materials with the ditopic 4, 4?-diaminodiphenylmethane ligand: Synthesis, structure characterization and luminescent properties
Chisca D, et al.
Polyhedron, 192, 114844-114844 (2020)
Jessica M Labonté et al.
The ISME journal, 9(11), 2386-2399 (2015-04-08)
Viral infections dynamically alter the composition and metabolic potential of marine microbial communities and the evolutionary trajectories of host populations with resulting feedback on biogeochemical cycles. It is quite possible that all microbial populations in the ocean are impacted by
Cong Hu et al.
Journal of chromatography. A, 1300, 165-172 (2013-06-04)
In this work, amino modified multi-walled carbon nanotubes/polydimethylsiloxane (multi-walled carbon nanotubes-4,4'-diaminodiphenylmethane/polydimethylsiloxane, MWCNTs-DDM/PDMS) was synthesized, and utilized as a novel coating for stir bar sorptive extraction (SBSE) of seven phenols (phenol, 2-chlorophenol, 2-nitrophenol, 4-nitrophenol, 2,4-dimethylphenol, p-choro-m-cresol and 2,4,6-trichlorphenol) in environmental water
Carcinogenic and chronic effects of 4,4'-diaminodiphenylmethane, an epoxyresin hardener.
R Schoental
Nature, 219(5159), 1162-1163 (1968-09-14)
Xiaoli Sun et al.
Journal of chromatography. A, 1343, 33-41 (2014-04-15)
A simple and fast method for both dummy template selection and polymer composition optimization is proposed here. A series of dummy templates for bisphenols imprinting were screened by running them on a non-imprinted polymer (NIP) column with porogen solvent as

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