330744
四丙基高钌酸铵
97%
别名:
TPAP
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
线性分子式:
(CH3CH2CH2)4NRuO4
化学文摘社编号:
分子量:
351.43
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Assay:
97%
Form:
solid
Quality Level
assay
97%
form
solid
reaction suitability
core: ammonium, reagent type: oxidant
mp
~160 °C (dec.) (lit.)
functional group
amine
SMILES string
[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
InChI
1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;
InChI key
NQSIKKSFBQCBSI-UHFFFAOYSA-N
General description
过钌酸四丙基铵是一种温和的氧化剂，可用于将醇氧化为相应的羰基化合物。它是一种不挥发、空气稳定、易溶的试剂，可以与合适的助氧化剂以化学计量或催化形式使用。
Application
过钌酸四丙基铵（TPAP）可以作为催化剂用于：
TPAP也可作为氧化剂用于：
- 通过氧化反应将硫化物转化为砜。
- 烯丙基醇的异构化，从而生成相应的饱和羰基衍生物。
- 与N-甲基吗啉-N-氧化物（NMO）一起，用于将乙二醇裂解为羧酸。
TPAP也可作为氧化剂用于：
- 将苄醇氧化为苯甲醛，将甾醇氧化为相应的酮。
- 将N，N′-二羟基咪唑烷酮转换为硝酰基硝基氧自由基。
- 将羟基取代的三-N-三氟硼酸叔丁基铵氧化为醛和酮，且不伴有碳-硼键的断裂。
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2
存储类别
5.1B - Oxidizing hazardous materials
商品
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
Ulyana Munoz Acuña et al.
Anticancer research, 37(4), 1617-1623 (2017-04-05)
The survival rate of women diagnosed with triple-negative breast-cancer (TNBC) remains low. Hence, this study aimed at the chemical and biological optimization of furanosteroid derivatives for the treatment of this type of malignancy using TNBC cells. Semi-synthetic analogs of wortmannolone
Gary A Molander et al.
Journal of the American Chemical Society, 128(30), 9634-9635 (2006-07-27)
Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates containing both primary and secondary hydroxyl groups were oxidized in moderate to excellent yields with complete retention of the trifluoroborate
Tetrapropylammonium Perruthenate, Pr4N+RuO4 -, TPAP: A Catalytic Oxidant for Organic Synthesis
Steven V.L, et al.
Synthesis, 7, 639-666 (1994)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 330744-250MG | 04061826726204 |
| 330744-1G | 04061826726198 |