332798
2,3,4,5-四氟硝基苯
99%
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关于此项目
线性分子式:
HC6F4NO2
化学文摘社编号:
分子量:
195.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
226-972-8
MDL number:
Assay:
99%
Form:
liquid
InChI key
MKMDVNZEIQDZEP-UHFFFAOYSA-N
InChI
1S/C6HF4NO2/c7-2-1-3(11(12)13)5(9)6(10)4(2)8/h1H
SMILES string
[O-][N+](=O)c1cc(F)c(F)c(F)c1F
assay
99%
form
liquid
refractive index
n20/D 1.473 (lit.)
bp
80 °C/24 mmHg (lit.)
density
1.618 g/mL at 25 °C (lit.)
functional group
fluoro, nitro
General description
2,3,4,5-Tetrafluoronitrobenzene is a polyfluoroarene. Mercuration of 2,3,4,5-tetrafluoronitrobenzene has been reported. It reacts with thioureas to afford para substituted diaryl sulphides. The nucleophilic aromatic substitution reactions of 2,3,4,5-tetrafluoronitrobenzene with methanol has been reported.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
177.8 °F - closed cup
flash_point_c
81 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Organomercury compounds: XVII. The mercuration of 1, 2, 3, 4-tetrafluorobenzene, 1, 2, 3, 5-tetrafluorobenzene, 2, 3, 5, 6-tetrafluoroanisole, and 2, 3, 4, 5-tetrafluoronitrobenzene.
Albrecht HB and Deacon GB.
Journal of Organometallic Chemistry, 57(1), 77-86 (1973)
Reductively activated ?Polar? nucleophilic aromatic substitution. III: The reactions of polyfluoronitrobenzenes with methanol.
Niat M, et al.
Tetrahedron Letters, 35(48), 9059-9062 (1994)
Aromatic polyfluoro-compounds-LIII reactions of polyflouroarenes with thioureas.
Coe PL, et al.
Tetrahedron, 28(1), 105-109 (1972)
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