332895
三氯硫氯甲烷
≥96%
别名:
全氯甲硫醇
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关于此项目
线性分子式:
CCl3SCl
化学文摘社编号:
分子量:
185.89
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
209-840-4
MDL number:
Assay:
≥96%
Form:
liquid
InChI key
RYFZYYUIAZYQLC-UHFFFAOYSA-N
InChI
1S/CCl4S/c2-1(3,4)6-5
SMILES string
ClSC(Cl)(Cl)Cl
vapor density
6.41 (vs air)
vapor pressure
2.02 psi ( 20 °C)
assay
≥96%
form
liquid
refractive index
n20/D 1.537 (lit.)
bp
146-148 °C (lit.)
density
1.7 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
Application
全氯甲硫醇可用于制备：
- 通过与乙酸银和三氟乙酸银的异质反应，得到三氯甲基硫酰乙酸酯和三氯甲基硫酰三氟乙酸酯
- 三氯甲基二硫化物
- 烷基原碳酸酯
- 三硫代碳酸盐
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Some reactions of trichloromethanesulfenyl chloride with alcohols and thiols.
Islam NB, et al.
Journal of Chemical and Engineering Data, 30(4), 509-512 (1985)
Lin Du et al.
The journal of physical chemistry. A, 111(23), 4944-4949 (2007-05-22)
Two novel species, trichloromethanesulfenyl acetate, CCl(3)SOC(O)CH(3), and trichloromethanesulfenyl trifluoroacetate, CCl(3)SOC(O)CF(3), have been generated in situ by the heterogeneous reactions between trichloromethanesulfenyl chloride, CCl(3)SCl, and corresponding silver salts, silver acetate (AgOC(O)CH(3)) and silver trifluoroacetate (AgOC(O)CF(3)), respectively. Photoelectron spectroscopy and quantum chemical
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