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关于此项目
线性分子式:
[(CH3)3Si]3P
化学文摘社编号:
分子量:
250.54
UNSPSC Code:
12161700
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三(三甲基硅烷基)膦, 95%
Quality Segment
assay
95%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n
bp
243-244 °C (lit.)
density
0.863 g/mL at 25 °C (lit.)
functional group
phosphine
storage temp.
2-8°C
SMILES string
C[Si](C)(C)P([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C9H27PSi3/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
InChI key
OUMZKMRZMVDEOF-UHFFFAOYSA-N
Application
三(三甲基硅烷基)磷化氢(P(TMS)3)可用作前体以合成:
- 磷化铟(InP)和磷化铟镓(InGaP)纳米晶体,III-V型半导体。
- 手性TMS-磷杂环戊烷,可进一步用于针对不对称催化合成各种二磷杂环戊烷配体。
警示词
Danger
Hazard Classifications
Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 3
靶器官
Respiratory system
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
闪点 (F)
Not applicable
闪点 (°C)
Not applicable
PPE(个人防护设备)
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

