335363
[1,3-双(二苯基膦)丙烷]二氯化镍(II)
powder
别名:
(1,3-dppp)NiCl2, 1,3-双(二苯基膦)丙烷氯化镍(II), 镍 (dppp) Cl2
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关于此项目
线性分子式:
[(C6H5)2P(CH2)3P(C6H5)2]NiCl2
化学文摘社编号:
分子量:
542.04
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
[1,3-双(二苯基膦)丙烷]二氯化镍(II),
form
powder
Quality Level
reaction suitability
core: nickel, reaction type: Cross Couplings, reagent type: catalyst
mp
213 °C (dec.) (lit.)
SMILES string
Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
InChI
1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI key
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
Application
[1,3-双(二苯基膦)丙烷]二氯化镍(II)可作为金属富勒烯配合物还原法合成的前体。
以下过程的催化剂：
- 嵌段共聚噻吩的合成
- 卤代芳烃与芳基硼酸的 Suzuki-Miyaura 交叉偶联反应
- 固态复缩聚反应
- 聚（3-烷氧基噻吩）的聚合
- 大环内酯类抗生素 aplyronine A 的 C1-C19 非对映选择性 Nozaki-Hiyama-Kishi 偶联反应
- 共轭聚合物的转移缩聚
signalword
Danger
Hazard Classifications
Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
相关内容
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 335363-5G | 04061826739839 |
| 335363-25G | 04061833546789 |