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Merck
CN

335363

Sigma-Aldrich

[1,3-双(二苯基膦)丙烷]二氯化镍(II)

powder

别名:

(1,3-dppp)NiCl2, 1,3-双(二苯基膦)丙烷氯化镍(II), 镍 (dppp) Cl2

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关于此项目

线性分子式:
[(C6H5)2P(CH2)3P(C6H5)2]NiCl2
化学文摘社编号:
15629-92-2
分子量:
542.04
MDL编号:
MFCD00015318
UNSPSC代码:
12161600
PubChem化学物质编号:
24860309
NACRES:
NA.22

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产品名称

[1,3-双(二苯基膦)丙烷]二氯化镍(II),

表单

powder

质量水平

100

反应适用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

213 °C (dec.) (lit.)

SMILES字符串

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI key

ZBQUMMFUJLOTQC-UHFFFAOYSA-L

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相关类别

应用

[1,3-双(二苯基膦)丙烷]二氯化镍(II)可作为金属富勒烯配合物还原法合成的前体。
以下过程的催化剂：
  • 嵌段共聚噻吩的合成
  • 卤代芳烃与芳基硼酸的 Suzuki-Miyaura 交叉偶联反应
  • 固态复缩聚反应
  • 聚（3-烷氧基噻吩）的聚合
  • 大环内酯类抗生素 aplyronine A 的 C1-C19 非对映选择性 Nozaki-Hiyama-Kishi 偶联反应
  • 共轭聚合物的转移缩聚

象形图

Health hazardExclamation mark
GHS08,GHS07

警示用语：

Danger

危险分类

Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT5778
MKCN8457
0000094470
MKCL7329
0000071214

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The ?2 Complex of Nickel Bis (diphenylphosphanyl) propane with Fullerene
Konarev DV, et al.
European Journal of Inorganic Chemistry, 2011(6), 816-820 (2011)
Renxuan Xie et al.
Nature communications, 11(1), 893-893 (2020-02-16)
The glass transition temperature (Tg) is a key property that dictates the applicability of conjugated polymers. The Tg demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable
Xiaoyu Li et al.
Nature communications, 8, 15909-15909 (2017-06-27)
Micelles formed by the self-assembly of block copolymers in selective solvents have attracted widespread attention and have uses in a wide variety of fields, whereas applications based on their electronic properties are virtually unexplored. Herein we describe studies of solution-processable
Tomasz Jarosz et al.
Polymers, 11(2) (2019-04-10)
A type of graft copolymer based on polysiloxane and regioregular poly(3-hexylthiophene) (P3HT) has been synthesised and its properties have been studied alongside those of its parent conjugated polymer-regioregular P3HT. Electrochemical analysis has revealed more significant changes in conformation of the
Caitlyn M Wolf et al.
Soft matter, 15(25), 5067-5083 (2019-06-12)
The molecular morphology and dynamics of conjugated polymers in the bulk solid state play a significant role in determining macroscopic charge transport properties. To understand this relationship, molecular dynamics (MD) simulations and quantum mechanical calculations are used to evaluate local
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