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Merck
CN

335908

氯甲酸异丙酯 溶液

1.0 M in toluene

别名:

1-甲基乙基氯甲酸酯, 异丙氧羰基氯, 氯甲酸 2-丙酯, 氯碳酸异丙酯

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线性分子式:
(CH3)2CHOCOCl
化学文摘社编号:
分子量:
122.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506416
Form:
liquid
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产品名称

氯甲酸异丙酯 溶液, 1.0 M in toluene

InChI

1S/C4H7ClO2/c1-3(2)7-4(5)6/h3H,1-2H3

SMILES string

CC(C)OC(Cl)=O

InChI key

IVRIRQXJSNCSPQ-UHFFFAOYSA-N

form

liquid

concentration

1.0 M in toluene

density

0.892 g/mL at 25 °C

functional group

chloro

storage temp.

2-8°C

Quality Level

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Application

异丙基氯仿用于通过环己烯的烷基化制备异丙基环己烷。在倍半氯化乙基铝存在下,通过与油酸反应,也可用于制备 10-异丙基十八烷酸

General description

已经报道了在 25℃ 下在各种溶剂中氯甲酸异丙酯的溶剂分解的特定速率。

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

42.8 °F - closed cup

flash_point_c

6 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
易制毒化学品(3类)
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Malcolm J D'Souza et al.
International journal of molecular sciences, 10(3), 862-879 (2009-04-29)
Specific rates of solvolysis at 25 degrees C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at
Biermann et al.
Angewandte Chemie (International ed. in English), 38(24), 3675-3677 (2000-01-29)
The formal addition of propane to nonactivated double bonds can be achieved with isopropyl chloroformate (2) in the presence of Et(3)Al(2)Cl(3). Thus, a 1:1 mixture of 10-isopropyloctadecanoic acid (3) and the 9-regioisomer is formed from oleic acid (1). The reaction
Hatem Salama Mohamed Ali et al.
Amino acids, 46(9), 2241-2257 (2014-06-19)
Whereas an abundance of literature is available on the occurrence of common proteinogenic amino acids (AAs) in edible fruits of the date palm (Phoenix dactylifera L.), recent reports on non-proteinogenic (non-coded) AAs and amino components are scarce. With emphasis on
Emmanuel O Mogusu et al.
Analytical and bioanalytical chemistry, 407(18), 5249-5260 (2015-05-15)
To assess sources and degradation of the herbicide glyphosate [N-(phosphonomethyl) glycine] and its metabolite AMPA (aminomethylphosphonic acid), concentration measurements are often inconclusive and even (13)C/(12)C analysis alone may give limited information. To advance isotope ratio analysis of an additional element

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