335908
氯甲酸异丙酯 溶液
1.0 M in toluene
别名:
1-甲基乙基氯甲酸酯, 异丙氧羰基氯, 氯甲酸 2-丙酯, 氯碳酸异丙酯
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关于此项目
线性分子式:
(CH3)2CHOCOCl
化学文摘社编号:
分子量:
122.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
506416
Form:
liquid
form
liquid
Quality Level
concentration
1.0 M in toluene
density
0.892 g/mL at 25 °C
functional group
chloro
storage temp.
2-8°C
SMILES string
CC(C)OC(Cl)=O
InChI
1S/C4H7ClO2/c1-3(2)7-4(5)6/h3H,1-2H3
InChI key
IVRIRQXJSNCSPQ-UHFFFAOYSA-N
General description
已经报道了在 25℃ 下在各种溶剂中氯甲酸异丙酯的溶剂分解的特定速率。
Application
异丙基氯仿用于通过环己烯的烷基化制备异丙基环己烷。在倍半氯化乙基铝存在下，通过与油酸反应，也可用于制备 10-异丙基十八烷酸
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
wgk
WGK 2
法规信息
危险化学品
易制毒化学品（3类）
此项目有
Malcolm J D'Souza et al.
International journal of molecular sciences, 10(3), 862-879 (2009-04-29)
Specific rates of solvolysis at 25 degrees C for isopropyl chloroformate (1) in 24 solvents of widely varying nucleophilicity and ionizing power, plus literature values for studies in water and formic acid, are reported. Previously published solvolytic rate constants at
Biermann et al.
Angewandte Chemie (International ed. in English), 38(24), 3675-3677 (2000-01-29)
The formal addition of propane to nonactivated double bonds can be achieved with isopropyl chloroformate (2) in the presence of Et(3)Al(2)Cl(3). Thus, a 1:1 mixture of 10-isopropyloctadecanoic acid (3) and the 9-regioisomer is formed from oleic acid (1). The reaction
Hatem Salama Mohamed Ali et al.
Amino acids, 46(9), 2241-2257 (2014-06-19)
Whereas an abundance of literature is available on the occurrence of common proteinogenic amino acids (AAs) in edible fruits of the date palm (Phoenix dactylifera L.), recent reports on non-proteinogenic (non-coded) AAs and amino components are scarce. With emphasis on
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 335908-100ML | 04061836691967 |
| 335908-800ML | 04061836691974 |