336467
萘二甲酰亚胺
technical grade
别名:
NSC 25094
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经验公式（希尔记法）:
C11H7NO
化学文摘社编号:
分子量:
169.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
204-973-4
MDL number:
产品名称
萘二甲酰亚胺, technical grade
form
solid
InChI key
GPYLCFQEKPUWLD-UHFFFAOYSA-N
InChI
1S/C11H7NO/c13-11-8-5-1-3-7-4-2-6-9(12-11)10(7)8/h1-6H,(H,12,13)
SMILES string
O=C1Nc2cccc3cccc1c23
grade
technical grade
mp
173-178 °C (lit.)
solubility
methanol: soluble 25 mg/mL, clear to slightly hazy, yellow to brown
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Application
- Reactant in photo-Fries rearrangement
- Reactant in preparation of potential antitumor agents
- Reactant in synthesis of inhibitors of thymidylate synthase
Benz[cd]indol-2(1H)-one was used in the synthesis of 2-oxo-1,2-dihydrobenzo[cd]indole-6-sulfonamide analog, novel Mycobacterium protein tyrosine phosphatase B (mPTPB) inhibitor.
General description
Benz[cd]indol-2(1H)-one is also referred as naphtholactam.
Saeed I Khan et al.
Acta crystallographica. Section C, Crystal structure communications, 68(Pt 1), o1-o6 (2012-01-10)
Weakly diffracting crystals of benz[cd]indol-2(1H)-one (naphtholactam), C(11)H(7)NO, were unsuitable for data collection by early photographic methods. However, a diffractometer data set collected at room temperature in 1989 was solved and refined. The peak scans were broad, and the results indicated
Lan Chen et al.
ACS medicinal chemistry letters, 1(7), 355-359 (2010-12-01)
Mycobacterium protein tyrosine phosphatase B (mPTPB) is an essential virulence factor required for Mycobacterium tuberculosis (Mtb) survival in host macrophages. Consequently, mPTPB represents an exciting new target with a completely novel mechanism of action. We screened a library of 7,500
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Quantum dots (QDs): Semiconductor nanoparticles with diverse applications including displays, lighting, and biomedical imaging.
Fries重排反应是一类重要的有机人名反应，它涉及在催化剂存在下加热时将酚酯转化成邻位或对位酰基酚。
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