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线性分子式:
CF3OC6H4NH2
化学文摘社编号:
分子量:
177.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-317-5
Beilstein/REAXYS Number:
2090209
MDL number:
产品名称
4-(三氟甲氧基)苯胺, 98%
InChI key
XUJFOSLZQITUOI-UHFFFAOYSA-N
InChI
1S/C7H6F3NO/c8-7(9,10)12-6-3-1-5(11)2-4-6/h1-4H,11H2
SMILES string
Nc1ccc(OC(F)(F)F)cc1
assay
98%
form
liquid
refractive index
n20/D 1.463 (lit.)
bp
73-75 °C/10 mmHg (lit.)
density
1.32 g/mL at 20 °C (lit.)
functional group
fluoro
Quality Level
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Application
4-(三氟甲氧基)苯胺用于合成:
- 含氟液晶元的侧基液晶聚甲基丙烯酸酯
- 3-(喹啉-3-基)丙烯酸酯的衍生物
- 分子筛存在下与氟化甲醛缩合的多种新型Shiff碱
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT RE 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
177.8 °F - closed cup
flash_point_c
81 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Addition of Me3SiCN to trifluoromethyl derivates of N-(pyridylmethylidene) anilines catalyzed by Lewis acids.
Iovel I, et al.
Applied Organometallic Chemistry, 15(9), 733-743 (2001)
Microwave-assisted multistep synthesis of functionalized 4-arylquinolin-2 (1 H)-ones using palladium-catalyzed cross-coupling chemistry.
Glasnov TN, et al.
The Journal of Organic Chemistry, 70(10), 3865-3870 (2005)
Synthesis of liquid-crystalline poly (meth) acrylates with 4-trifluoromethoxy-azobenzene mesogenic side-groups.
Prescher D, et al.
Journal of Fluorine Chemistry, 74(2), 185-189 (1995)
M Tugnait et al.
Journal of pharmaceutical and biomedical analysis, 28(5), 875-885 (2002-06-01)
A combination of 19F, 1H NMR and HPLC-NMR spectroscopic approaches have been used to quantify and identify the urinary-excreted metabolites of 4-trifluoromethoxyaniline (4-TFMeA) and its [13C]-labelled acetanilide following i.p. administration at 50 mg/kg to rats. The major metabolite excreted in
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