337722
1,3,5-三苄基六氢-1,3,5-三嗪
98%
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关于此项目
经验公式（希尔记法）:
C24H27N3
化学文摘社编号:
分子量:
357.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
219-831-7
MDL number:
产品名称
1,3,5-三苄基六氢-1,3,5-三嗪, 98%
InChI key
VWVZIRPJPFJGFE-UHFFFAOYSA-N
InChI
1S/C24H27N3/c1-4-10-22(11-5-1)16-25-19-26(17-23-12-6-2-7-13-23)21-27(20-25)18-24-14-8-3-9-15-24/h1-15H,16-21H2
SMILES string
C1N(CN(CN1Cc2ccccc2)Cc3ccccc3)Cc4ccccc4
assay
98%
form
solid
bp
100 °C/0.005 mmHg (lit.)
mp
49-51 °C (lit.)
functional group
phenyl
Application
1,3,5-Tribenzylhexahydro-1,3,5-triazine was used:
- in the synthesis of alkyl β-aminocarboxylates via trifluoromethanesulfonic acid catalyzed reaction with ketene silyl acetals
- as ligand to study the assembling process of a heterogeneous Cr-based single-site ethylene trimerization catalyst by X-ray absorption spectroscopy
- as ligand during conversion of Phillips Cr/SiO2 polymerisation catalyst to ethylene trimerisation catalyst after assembling new active sites on the silica surface
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Trifluoromethanesulfonic acid-promoted reaction of hexahydro-1, 3, 5-triazines with ketene silyl acetals. convenient synthesis of alkyl ?-aminocarboxylates.
Ikeda K, et al.
Tetrahedron Letters, 24(9), 913-916 (1983)
Cristina N Nenu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(18), 4756-4763 (2006-04-07)
X-ray absorption spectroscopy at the Cr K- and L(2,3)-edges was used to study the assembling process of a heterogeneous Cr-based single-site catalyst. The starting point was a Phillips-type system with monochromate species anchored on a silica surface, which was first
Turning a Cr-based heterogeneous ethylene polymerisation catalyst into a selective ethylene trimerisation catalyst.
Nenu CN, et al.
J. Mol. Catal. A: Chem., 269(1), 5-11 (2007)
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