337773
氯二异丙基膦
96%, liquid
可持续性特点
别名:
Diisopropylphosphine chloride
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关于此项目
线性分子式:
[(CH3)2CH]2PCl
化学文摘社编号:
分子量:
152.60
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
氯二异丙基膦, 96%
Quality Segment
assay
96%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Arylations
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
refractive index
n
bp
69 °C/33 mmHg (lit.)
density
0.959 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CC(C)P(Cl)C(C)C
InChI
1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
InChI key
JZPDBTOWHLZQFC-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This intermediate enables synthesis of organophosphine ligands and phosphinites through direct reaction with alcohols and organometallic reagents. It reduces reliance on commercial ligands and enables tailored catalyst development. Click here for more information.
Application
氯二异丙基膦可用于：
- 通过格氏反应与 4-氯苯乙烯反应合成对-苯乙烯二异丙基膦。
- 作为与一种磷化试剂，与 [Cp2Zr（1-丁烯）（DMAP）]（Cp =环戊二烯基；DMAP = 4-（二甲氨基）吡啶）结合，可用于炔烃的锆磷化，形成锆烯基膦。
- 一种发光混合供体铂 POCN 钳形化合物（通过环金属化法）。
警示词
Danger
危险代码
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
怎么回事？
WGK 3
闪点 (F)
39.2 °F - closed cup
闪点 (°C)
4 °C - closed cup
PPE（个人防护设备）
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter