338710
氯甲酸(-)-1-(9-芴)乙酯 溶液
18 mM in acetone, derivatization grade (chiral)
别名:
(-)-FLEC
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关于此项目
经验公式（希尔记法）:
C16H13ClO2
化学文摘社编号:
分子量:
272.73
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
产品名称
氯甲酸(-)-1-(9-芴)乙酯 溶液, 18 mM in acetone, derivatization grade (chiral)
InChI
1S/C16H13ClO2/c1-10(19-16(17)18)15-13-8-4-2-6-11(13)12-7-3-5-9-14(12)15/h2-10,15H,1H3
SMILES string
CC(OC(Cl)=O)C1c2ccccc2-c3ccccc13
InChI key
SFRVOKMRHPQYGE-UHFFFAOYSA-N
grade
derivatization grade (chiral)
concentration
18 mM in acetone
density
0.79 g/mL at 25 °C
functional group
chloro
storage temp.
2-8°C
Quality Level
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General description
(-)-1-(9-Fluorenyl)ethyl chloroformate is mostly used as an in-capillary derivatization agent for the separation of amino acid (AA) derivatives by micellar electrokinetic chromatography (MEKC).
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F
flash_point_c
-17.0 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
易制毒化学品（3类）
危险化学品
此项目有
In-capillary derivatization with (-)-1-(9-fluorenyl) ethyl chloroformate as chiral labeling agent for the electrophoretic separation of amino acids.
Fradi I, et al.
Journal of Chromatography A, 1323, 338-347 (2014)
Radu-Cristian Moldovan et al.
Journal of chromatography. A, 1513, 1-17 (2017-08-02)
Over the last 30years, (±)-1-(9-fluorenyl)ethyl chloroformate ((±)-FLEC) was used as a chiral derivatizing agent in various analytical applications involving a wide range of endogenous, pharmaceutical and environmentally relevant molecules. This comprehensive review aims to present all the significant aspects related
Radu-Cristian Moldovan et al.
Journal of chromatography. A, 1564, 199-206 (2018-06-19)
A targeted CE-MS approach was developed for the chiral analysis of biologically relevant amino acids in artificial cerebrospinal fluid (aCSF). In order to achieve chiral resolution, the five amino acids (Ser, Asn, Asp, Gln and Glu) were derivatized with (+)-1-(9-fluorenyl)ethyl
Radu-Cristian Moldovan et al.
Journal of chromatography. A, 1590, 80-87 (2019-01-15)
D-amino acids (AA) analysis is becoming more and more relevant for metabolomics, therefore new analytical tools need to be developed. A common approach to achieve AA enantioseparation is chiral derivatization. Among the chiral derivatization reagents, (+) or (-)-1-(9-fluorenyl) ethyl chloroformate
Radu-Cristian Moldovan et al.
Journal of chromatography. A, 1467, 400-408 (2016-08-25)
In the context of bioanalytical method development, process automatization is nowadays a necessity in order to save time, improve method reliability and reduce costs. For the first time, a fully automatized micellar electrokinetic chromatography-mass spectrometry (MEKC-MS) method with in-capillary derivatization
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