338923
1-苯基-2-(三甲基硅)乙炔
99%
别名:
1-苯基-2-(三甲基硅烷基)乙炔, 三甲基(苯乙炔基)硅烷, 苯基乙炔基三甲基硅烷
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关于此项目
线性分子式:
C6H5C≡CSi(CH3)3
化学文摘社编号:
分子量:
174.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3088678
Assay:
99%
Form:
liquid
InChI
1S/C11H14Si/c1-12(2,3)10-9-11-7-5-4-6-8-11/h4-8H,1-3H3
SMILES string
C[Si](C)(C)C#Cc1ccccc1
InChI key
UZIXCCMXZQWTPB-UHFFFAOYSA-N
assay
99%
form
liquid
refractive index
n20/D 1.528 (lit.)
bp
87-88 °C/9 mmHg (lit.)
density
0.886 g/mL at 25 °C (lit.)
functional group
phenyl
Quality Level
General description
1-苯基-2-三甲基甲硅烷基乙炔是 SiMe3取代炔烃。它可与炔丙醇和烯丙醇偶联。目前已有报道称，可通过各种过渡金属催化剂聚合 1-苯基-2-三甲基甲硅烷基乙炔。
Application
1-苯基-2-三甲基甲硅烷基乙炔用于制备供体稳定的 Pt-η2-炔烃复合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
165.2 °F - closed cup
flash_point_c
74 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
G G K S Narayana Kumar et al.
Organic & biomolecular chemistry, 10(36), 7347-7355 (2012-08-11)
Allyltrimethylsilane (allyl-TMS) reacts with propargylic alcohols 1a-1d in the presence of 10% Bi(OTf)(3) in [BMIM][BF(4)] solvent to furnish the corresponding 1,5-enynes in respectable isolated yields (87-93%) at room temperature. The utility of Bi(OTf)(3) as a superior catalyst was demonstrated in
Electro-optical and Electrochemical Properties of a Disubstituted Polyacetylene: Poly (1-phenyl-2-trimethylsilylacetylene)
Choi HK, et al.
Mol. Cryst. Liq. Cryst., 563, 153-158 (2012)
Thermal and photochemical silicon-carbon bond activation in donor-stabilized platinum (0)-alkyne complexes.
Muller C, et al.
Organometallics, 21(6), 1190-1196 (2002)
Polymerization of 1-phenyl-2-trimethylsilylacetylene by transition metal catalysts.
Gal Y-S and Choi S-K.
Journal of Polymer Science Part A: Polymer Chemistry, 25(8), 2323-2326 (1987)
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