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338923

1-苯基-2-(三甲基硅)乙炔

Name: 1-苯基-2-(三甲基硅)乙炔
Brand: ALDRICH

99%

别名:

1-苯基-2-(三甲基硅烷基)乙炔, 三甲基(苯乙炔基)硅烷, 苯基乙炔基三甲基硅烷

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关于此项目

线性分子式:

C₆H₅C≡CSi(CH₃)₃

化学文摘社编号:

2170-06-1

分子量:

174.31

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24860590

MDL number:

MFCD00054860

Beilstein/REAXYS Number:

3088678

Assay:

99%

Form:

liquid

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属性

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.528 (lit.)

bp

87-88 °C/9 mmHg (lit.)

density

0.886 g/mL at 25 °C (lit.)

functional group

phenyl

SMILES string

C[Si](C)(C)C#Cc1ccccc1

InChI

1S/C11H14Si/c1-12(2,3)10-9-11-7-5-4-6-8-11/h4-8H,1-3H3

InChI key

UZIXCCMXZQWTPB-UHFFFAOYSA-N

说明

General description

1-苯基-2-三甲基甲硅烷基乙炔是 SiMe₃取代炔烃。它可与炔丙醇和烯丙醇偶联。目前已有报道称，可通过各种过渡金属催化剂聚合 1-苯基-2-三甲基甲硅烷基乙炔。

Application

1-苯基-2-三甲基甲硅烷基乙炔用于制备供体稳定的 Pt-η²-炔烃复合物。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Facile coupling of propargylic, allylic and benzylic alcohols with allylsilane and alkynylsilane, and their deoxygenation with Et3SiH, catalyzed by Bi(OTf)3 in [BMIM][BF4] ionic liquid (IL), with recycling and reuse of the IL.

G G K S Narayana Kumar et al.

Organic & biomolecular chemistry, 10(36), 7347-7355 (2012-08-11)

Allyltrimethylsilane (allyl-TMS) reacts with propargylic alcohols 1a-1d in the presence of 10% Bi(OTf)(3) in [BMIM][BF(4)] solvent to furnish the corresponding 1,5-enynes in respectable isolated yields (87-93%) at room temperature. The utility of Bi(OTf)(3) as a superior catalyst was demonstrated in

Electro-optical and Electrochemical Properties of a Disubstituted Polyacetylene: Poly (1-phenyl-2-trimethylsilylacetylene)

Choi HK, et al.

Mol. Cryst. Liq. Cryst., 563, 153-158 (2012)

Polymerization of 1-phenyl-2-trimethylsilylacetylene by transition metal catalysts.

Gal Y-S and Choi S-K.

Journal of Polymer Science Part A: Polymer Chemistry, 25(8), 2323-2326 (1987)

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全球贸易项目编号

货号	GTIN
338923-50G	04061837581106
338923-10G	04061826745649