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339555

溴甲基苯基砜

Name: 溴甲基苯基砜
Brand: ALDRICH

98%

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关于此项目

线性分子式:

C₆H₅SO₂CH₂Br

化学文摘社编号:

19169-90-5

分子量:

235.10

NACRES:

NA.22

PubChem Substance ID:

24860649

UNSPSC Code:

12352100

MDL number:

MFCD00034033

Assay:

98%

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属性

assay

98%

mp

51-53 °C (lit.)

functional group

bromo, sulfone

SMILES string

BrCS(=O)(=O)c1ccccc1

InChI

1S/C7H7BrO2S/c8-6-11(9,10)7-4-2-1-3-5-7/h1-5H,6H2

InChI key

SKIMEKUYIQHJQV-UHFFFAOYSA-N

说明

General description

Reaction of bromomethyl phenyl sulfone with potassium thiophenoxide in dimethyl formamide gave phenylthiomethyl phenyl sulfone. It undergoes disproportionation with KOH in DMSO at room temperature to yield methyl phenyl sulfone and dibromomethyl phenyl sulfone.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nucleophilic displacements alpha to sulfonyl groupings.

Bordwell FG and Jarvis BB.

The Journal of Organic Chemistry, 33(3), 1182-1185 (1968)

Base-induced disproportionation of halomethyl phenyl sulfones to methyl and dihalomethyl phenyl sulfones.

Galvagni M, et al.

The Journal of Organic Chemistry, 55(14), 4454-4456 (1990)

全球贸易项目编号

货号	GTIN
339555-5G	04061826752456