Quality Segment
assay
99%
form
liquid
refractive index
n20/D 1.461 (lit.)
bp
80 °C/50 mmHg (lit.)
density
1.622 g/mL at 25 °C (lit.)
functional group
bromo, fluoro
SMILES string
FC(F)(F)Oc1ccc(Br)cc1
InChI
1S/C7H4BrF3O/c8-5-1-3-6(4-2-5)12-7(9,10)11/h1-4H
InChI key
SEAOBYFQWJFORM-UHFFFAOYSA-N
General description
1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene.
Application
1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine.
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signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter