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文件

339652

轮环藤宁

Name: 轮环藤宁
Brand: ALDRICH

97%

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别名:

1,4,7,10-四氮环十二烷

经验公式（希尔记法）:

C₈H₂₀N₄

CAS号:

294-90-6

分子量:

172.27

Beilstein:

606114

MDL编号:

MFCD00066281

PubChem化学物质编号:

24860658

NACRES:

NA.23

质量水平

100

检测方案

97%

形式

solid

mp

110-113 °C (lit.)

SMILES字符串

C1CNCCNCCNCCN1

InChI

1S/C8H20N4/c1-2-10-5-6-12-8-7-11-4-3-9-1/h9-12H,1-8H2

InChI key

QBPPRVHXOZRESW-UHFFFAOYSA-N

一般描述

轮环藤宁是一种微环四胺（microcyclic tetramine），可用作与表面金属阳离子形成配位键的配体。它可用作合成前体。它可以通过二硫代草酰胺与过量溴乙烷的S-烷基化反应来制备。

应用

轮环藤宁是一种氮杂环（azamocrocycle），可用于开发检测金属离子的荧光纳米传感器。

象形图

GHS05,GHS06,GHS09

警示用语：

Danger

危险声明

H302 - H311 - H314 - H410

预防措施声明

P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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T1503

货号

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Selective hydrolysis of phosphate monoester by a supramolecular phosphatase formed by the self-assembly of a bis(Zn(2+)-cyclen) complex, cyanuric acid, and copper in an aqueous solution (cyclen = 1,4,7,10-tetraazacyclododecane).

Mohd Zulkefeli et al.

Inorganic chemistry, 50(20), 10113-10123 (2011-09-23)

In Nature, organized nanoscale structures such as proteins and enzymes are formed in aqueous media via intermolecular interactions between multicomponents. Supramolecular and self-assembling strategies provide versatile methods for the construction of artificial chemical architectures for controlling reaction rates and the

Synthesis of luminescent homo-dinuclear cationic lanthanide cyclen complexes bearing amide pendant arms through the use of copper catalysed (1,3-Huisgen, CuAAC) click chemistry.

Jennifer K Molloy et al.

Organic & biomolecular chemistry, 10(2), 314-322 (2011-11-11)

The design and synthesis of dinuclear-lanthanide complexes possessing triazole-based bridges, formed by using copper catalysed 1,3-cycloaddition reactions between heptadentate alkyne functionalised cyclen europium or terbium complexes and di-azides (CuAAC reactions), are described. While this click reaction worked well for the

11B NMR sensing of d-block metal ions in vitro and in cells based on the carbon-boron bond cleavage of phenylboronic acid-pendant cyclen (cyclen = 1,4,7,10-tetraazacyclododecane).

Masanori Kitamura et al.

Inorganic chemistry, 50(22), 11568-11580 (2011-10-21)

Noninvasive magnetic resonance imaging (MRI) including the "chemical shift imaging (CSI)" technique based on (1)H NMR signals is a powerful method for the in vivo imaging of intracellular molecules and for monitoring various biological events. However, it has the drawback

A modified cyclen azaxanthone ligand as a new fluorescent probe for Zn2+.

Hela Nouri et al.

Dalton transactions (Cambridge, England : 2003), 42(34), 12157-12164 (2013-07-11)

A new cyclen derivative L, bearing a methyl-chromeno-pyridinylidene hydrazone moiety, was synthesized and studied in MeOH, as potential fluorescent "OFF-on-ON" sensors for Zn(ii). Photophysical properties of this ligand being PET regulated, L was only weakly emissive in the absence of

A new synthesis of cyclen (1, 4, 7, 10-tetraazacyclododecane)

Weisman GR and Reed DP

The Journal of Organic Chemistry, 61(15), 5186-5187 (1996)

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