质量水平
方案
97%
表单
solid
mp
110-113 °C (lit.)
SMILES字符串
C1CNCCNCCNCCN1
InChI
1S/C8H20N4/c1-2-10-5-6-12-8-7-11-4-3-9-1/h9-12H,1-8H2
InChI key
QBPPRVHXOZRESW-UHFFFAOYSA-N
一般描述
轮环藤宁是一种微环四胺（microcyclic tetramine），可用作与表面金属阳离子形成配位键的配体。它可用作合成前体。它可以通过二硫代草酰胺与过量溴乙烷的S-烷基化反应来制备。
应用
轮环藤宁是一种氮杂环（azamocrocycle），可用于开发检测金属离子的荧光纳米传感器。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Azamacrocycle activated quantum dot for zinc ion detection
Ruedas-Rama MJ and Hall EAH
Analytical Chemistry, 80(21), 8260-8268 (2008)
Luís M P Lima et al.
Inorganic chemistry, 50(24), 12508-12521 (2011-11-11)
The syntheses of a new cyclen-based ligand L(2) containing four N-[2-(2-hydroxyethoxy)ethyl]acetamide pendant arms and of its lanthanide(III) complexes [LnL(2)(H(2)O)]Cl(3) (Ln = La, Eu, Tb, Yb, or Lu) are reported, together with a comparison with some Ln(III) complexes of a previously
Novel" multipoint" molecular recognition of nucleobases by a new zinc (II) complex of acridine-pendant cyclen (cyclen= 1, 4, 7, 10-tetraazacyclododecane)
Shionoya M, et al.
Journal of the American Chemical Society, 116(9), 3848-3859 (1994)
Choy Theng Loh et al.
Bioconjugate chemistry, 24(2), 260-268 (2013-01-09)
Pseudocontact shifts (PCS) from paramagnetic lanthanide ions present powerful long-range structural restraints for structural biology by NMR spectroscopy, but site-specific tagging of proteins with lanthanides remains a challenge, as most of the available lanthanide tags require proteins with single cysteine
A new synthesis of cyclen (1, 4, 7, 10-tetraazacyclododecane)
Weisman GR and Reed DP
The Journal of Organic Chemistry, 61(15), 5186-5187 (1996)
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