340537
4-溴原丁酸三甲酯
95%
别名:
4-溴-1,1,1-三甲氧基丁烷
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关于此项目
线性分子式:
Br(CH2)3C(OCH3)3
化学文摘社编号:
分子量:
227.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Form:
liquid
InChI
1S/C7H15BrO3/c1-9-7(10-2,11-3)5-4-6-8/h4-6H2,1-3H3
SMILES string
COC(CCCBr)(OC)OC
InChI key
QBLJMYITBNHQOT-UHFFFAOYSA-N
assay
95%
form
liquid
refractive index
n20/D 1.456 (lit.)
bp
70 °C/0.7 mmHg (lit.)
density
1.309 g/mL at 25 °C (lit.)
functional group
bromo, ether
storage temp.
2-8°C
Application
Trimethyl 4-bromoorthobutyrate was used in the synthesis of macrocyclic lactone (S)-curvularin. Grignard reagent derived from trimethyl 4-bromoorthobutyrate was used in the preparation of novel hapten 4-(17 β-hydroxy-3-oxoestra-4,9-dien-11-β-yl)butanoic acid, used in enzyme-linked immunosorbent assay (ELISA) for testosterone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
P N Rao et al.
Steroids, 57(4), 154-161 (1992-04-01)
A microplate enzyme-linked immunosorbent assay (ELISA) has been developed for the measurement of testosterone in plasma. The assay uses a heterologous system consisting of a novel hapten 4-(17 beta-hydroxy-3-oxoestra-4,9-dien-11 beta-yl)butanoic acid (1) conjugated to penicillinase (beta-lactamase). The key reaction in
A chemoenzymatic synthesis of the macrocyclic lactone (S)-curvularin.
Bracher F and Schulte B.
Natural Product Letters, 7(1), 65-68 (1995)
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