341010
碘化铋(III)
99%, powder
别名:
三碘化铋, 三碘铋烷
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关于此项目
经验公式（希尔记法）:
BiI3
化学文摘社编号:
分子量:
589.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-127-4
MDL number:
产品名称
碘化铋(III), 99%
InChI key
KOECRLKKXSXCPB-UHFFFAOYSA-K
InChI
1S/Bi.3HI/h;3*1H/q+3;;;/p-3
SMILES string
I[Bi](I)I
assay
99%
form
powder
reaction suitability
core: bismuth, reagent type: catalyst
mp
408 °C (lit.)
density
5.78 g/mL at 25 °C (lit.)
Quality Level
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Application
碘化铋(III)或三碘化铋无毒性，因此可作为环保催化剂使用。它可用作以下反应的催化剂：
- 水中的缩醛和缩酮的化学选择性脱保护反应。
- 硫脲和胺合成多取代胍的成胍反应。
- 羰基化合物的巯基化反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
The first bismuth (III)-catalyzed guanylation of thioureas
Cunha S and Rodrigues Jr MT
Tetrahedron Letters, 47(39), 6955-6956 (2006)
Environmentally friendly organic synthesis using bismuth compounds: bismuth (III) iodide catalyzed deprotection of acetals in water
Bailey AD, et al.
Tetrahedron Letters, 49(4), 691-694 (2008)
Bismuth (III) Halides and Sulfate as Highly Efficient Catalyst for the Sulfenylation of Carbonyl and Related Compounds1
Komatsu N, et al.
Synlett, 1995(09), 984-986 (1995)
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
R R Jia et al.
Amino acids, 31(1), 85-90 (2006-04-04)
New bioinorganic complexes of the aspartic acid with the antimony or bismuth triiodide were synthesized by a direct solid-solid reaction at room temperature. The formula of the complex is MI(3)[OOCCH(2)CH(NH(2))CO](2.5) x 2.5H(2)O (M = Sb, Bi). The complex may be
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