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343536

1-Boc-哌嗪

97%

别名:

哌嗪-1-甲酸叔丁酯

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关于此项目

经验公式（希尔记法）:
C9H18N2O2
化学文摘社编号:
57260-71-6
分子量:
186.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24861171
MDL number:
MFCD00075265
Beilstein/REAXYS Number:
879985
Assay:
97%
Form:
solid
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Quality Level

200

assay

97%

form

solid

mp

43-47 °C (lit.)

SMILES string

CC(C)(C)OC(=O)N1CCNCC1

InChI

1S/C9H18N2O2/c1-9(2,3)13-8(12)11-6-4-10-5-7-11/h10H,4-7H2,1-3H3

InChI key

CWXPZXBSDSIRCS-UHFFFAOYSA-N

General description

1-Boc-哌嗪是-Boc保护的哌嗪。1-Boc-哌嗪与芳基碘的CuBr/1，1′交叉偶联。研究报道了铋-2-萘酚（催化剂）和K3PO4（碱）。1-Boc-哌嗪与芳基卤化物发生布赫华-哈特威格偶联反应。碘催化无溶剂N-Boc保护可制备80%产率的1-Boc-哌嗪。

Application

1-Boc-哌嗪可用于：
  • （m·-苯氧基）苯基取代哌嗪衍生物系列的制备
  • 通过活性阳离子开环聚合合成α,β-聚（2-噁唑啉）脂聚合物期间的终止步骤。
  • 单取代哌嗪的制备，例如吲唑脱氧核糖核酸回旋酶抑制剂的合成

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF6566V
BCCJ2948
BCCJ4544
BCBW3835
BCBL4205V

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全球贸易项目编号

货号GTIN
343536-1G04061826758212
343536-25G04061826758229
343536-5G04061826758236