343854
甲醇-d3
99.8 atom % D
别名:
1,1,1-Trideuteromethanol, Methyl-d3 alcohol
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关于此项目
线性分子式:
CD3OH
化学文摘社编号:
分子量:
35.06
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
217-435-9
Beilstein/REAXYS Number:
1732010
MDL number:
Isotopic purity:
99.8 atom % D
Assay:
99% (CP)
Mass shift:
M+3
Form:
liquid
InChI key
OKKJLVBELUTLKV-FIBGUPNXSA-N
InChI
1S/CH4O/c1-2/h2H,1H3/i1D3
SMILES string
[2H]C([2H])([2H])O
isotopic purity
99.8 atom % D
assay
99% (CP)
form
liquid
expl. lim.
5.5-36.5 % (lit.)
Quality Level
impurities
≤0.05% water
water
refractive index
n20/D 1.327 (lit.)
bp
65 °C (lit.)
density
0.867 g/mL at 25 °C (lit.)
format
neat
mass shift
M+3
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General description
甲醇-d 3 是一种氘代 NMR 溶剂，可用于基于 NMR 的研究和分析。
Application
甲醇-d 3 可与三甲基铝反应制备 [Al (CH 3 ) 2OCD 3 3 ，用于二烷基铝醇盐和三烷基铝醚络合物的光谱分析。
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
target_organs
Eyes,Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
51.8 °F - closed cup
flash_point_c
11 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
美国出口管控产品
此项目有
Spectroscopic Studies of Dialkylaluminum Alkoxides and the Trialkyl-aluminum-Ether Complex. II. Assignments of Observed Frequencies
Tarao, R
Bulletin of the Chemical Society of Japan, 39(10), 2126-2132 (1966)
Paweł Tomza et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 197, 88-94 (2018-02-06)
Here we report ATR-IR spectroscopic study on the separation at a molecular level (microheterogeneity) and the degree of deviation of H2O/CH3OH and H2O/CD3OH mixtures from the ideal mixture. Of particular interest is the effect of isotopic substitution in methyl group
Władysław Wrzeszcz et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 188, 349-354 (2017-07-29)
Recently, we demonstrated the presence of microheterogeneity in binary mixtures of unlike alcohols. [RSC Adv. 2016, 6, 37195-37202] The aim of this work was examination if this phenomenon occurs also in the mixture of very similar alcohols like CH
Thierry Jauffrais et al.
Marine drugs, 10(6), 1360-1382 (2012-07-24)
Azaspiracid (AZA) poisoning has been reported following consumption of contaminated shellfish, and is of human health concern. Hence, it is important to have sustainable amounts of the causative toxins available for toxicological studies and for instrument calibration in monitoring programs
Jason S Adams et al.
Science (New York, N.Y.), 371(6529), 626-632 (2021-02-06)
Solvent molecules influence the reactions of molecular hydrogen and oxygen on palladium nanoparticles. Organic solvents activate to form reactive surface intermediates that mediate oxygen reduction through pathways distinct from reactions in pure water. Kinetic measurements and ab initio quantum chemical
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