344125
(R)-(+)-N,N-二甲基-1-二茂铁基乙胺
97%
别名:
(R)-(+)-[1-(二甲氨基)乙基]二茂铁
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关于此项目
经验公式（希尔记法）:
C14H19FeN
化学文摘社编号:
分子量:
257.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
assay
97%
form
liquid
optical activity
[α]20/D +13°, c = 1 in ethanol (5 h)
refractive index
n
bp
120-121 °C/0.7 mmHg (lit.)
density
1.222 g/mL at 20 °C (lit.)
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][CH]2)N(C)C
InChI
1S/C9H14N.C5H5.Fe/c1-8(10(2)3)9-6-4-5-7-9;1-2-4-5-3-1;/h4-8H,1-3H3;1-5H;/t8-;;/m1../s1
InChI key
ISOLNZQTVMCEOI-YCBDHFTFSA-N
Application
用于手性烯丙醇、轴向手性丙二烯羧酸酯的制备，以及酮的铑(I)催化不对称氢化硅烷化反应的配体。
(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine may be used as a starting material to synthesize:
- chiral 1,2-disubstituted ferrocenyl amino alcohols
- ferrocene-based P-chiral phosphine ligands
- optically active α-ferrocenyl tertiary amines
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter