345709
5-氧代十八烷酸甲酯
99%
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线性分子式:
CH3(CH2)12CO(CH2)3CO2CH3
化学文摘社编号:
分子量:
312.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
Form:
solid
InChI
1S/C19H36O3/c1-3-4-5-6-7-8-9-10-11-12-13-15-18(20)16-14-17-19(21)22-2/h3-17H2,1-2H3
SMILES string
CCCCCCCCCCCCCC(=O)CCCC(=O)OC
InChI key
BVRPGVKJUHZXTH-UHFFFAOYSA-N
assay
99%
form
solid
mp
58-60 °C (lit.)
functional group
ester, ketone
Quality Level
General description
Methyl 5-oxooctadecanoate is an ester.
Application
Methyl 5-oxooctadecanoate may be used in the synthesis of seven-, eight- and nine-membered monocyclic, bicyclic and tricyclic ring systems.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Sequenced reactions with samarium (II) iodide. Sequential intermolecular carbonyl addition/intramolecular nucleophilic acyl substitution for the preparation of seven-, eight-, and nine-membered carbocycles.
Molander GA and Alonso-Alija C.
The Journal of Organic Chemistry, 63(13), 4366-4373 (1998)
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