Quality Level
assay
97%
form
liquid
impurities
0.1% hydroquinone
refractive index
n20/D 1.472 (lit.)
bp
94-95 °C (lit.)
density
1.339 g/mL at 25 °C (lit.)
functional group
alkyl halide, bromo
storage temp.
2-8°C
SMILES string
CC(=C)CBr
InChI
1S/C4H7Br/c1-4(2)3-5/h1,3H2,2H3
InChI key
USEGQJLHQSTGHW-UHFFFAOYSA-N
General description
已经通过 IR 光谱研究了 3-溴-2-甲基丙烯中的旋转异构。
Application
3-溴-2-甲基丙烯可用于：
- 烯基亚胺的合成
- 合成 2-甲基丙烯基（“甲基烯丙基”）配合物，Cp * Os（η3-烯丙基）Br2
- 在手性相转移烷基化的研究中产生（S）-α-烷基半胱氨酸
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
44.6 °F - closed cup
flash_point_c
7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Rotational isomerism in 3-bromo, 2-methylpropene studied by ir spectroscopy.
Diallo AO.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 36(9), 799-803 (1980)
Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs).
Rodolphe Jazzar et al.
Angewandte Chemie (International ed. in English), 46(16), 2899-2902 (2007-03-14)
Synthesis of Hydride and Alkyl Compounds Containing the Cp* Os (η3-allyl) Fragment. Crystal Structures of Cp* Os (η3-C8H13) Br2 and [Cp* Os (η3-C4H7) Me (H2O)][BF4].
Mui HD, et al.
Organometallics, 18(17), 3264-3272 (1999)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 345830-25ML | 04061837083303 |
| 345830-5ML | 04061826760888 |