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Merck
CN

346179

三乙基膦 溶液

1.0 M in THF, liquid

别名:

PEt3, Triethylphosphorous solution

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关于此项目

线性分子式:
(C2H5)3P
化学文摘社编号:
分子量:
118.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352128
MDL number:
Beilstein/REAXYS Number:
969170
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产品名称

三乙基膦 溶液, 1.0 M in THF

form

liquid

Quality Level

reaction suitability

reagent type: ligand
reaction type: Arylations

concentration

1.0 M in THF

density

0.869 g/mL at 25 °C

functional group

phosphine

SMILES string

CCP(CC)CC

InChI

1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

RXJKFRMDXUJTEX-UHFFFAOYSA-N

Application

Catalyst for:
  • Regioselective formation of alcohols from hydrocarbonylation of alkenes
  • Bronsted acid-assisted synthesis of dihydropyrones from aromatic aldehydes and allenoates
  • Silaboration of enynes
  • Conversion of phenylacetic acids to phenylacetonitriles of benzonitriles
  • Thermal decomposition of platinum and palladium naphthalenediyl
  • Asymmetrical Morita-Baylis-Hillman reaction


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

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相关内容

Phosphine Ligand Application Guide


Sarah A Weicker et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(37), 13027-13034 (2015-08-01)
Silyl triflates of the form R4-n Si(OTf)n (n=1, 2; OTf=OSO3 CF3 ) are shown to activate carbon dioxide when paired with bulky alkyl-substituted Group 15 bases. Combinations of silyl triflates and 2,2,6,6-tetramethylpiperidine react with CO2 to afford silyl carbamates via a
Vitor L Martins et al.
Physical chemistry chemical physics : PCCP, 17(35), 23041-23051 (2015-08-15)
This work presents the physicochemical characterization of two ionic liquids (ILs) with small phosphonium cations, triethylpenthylphosphonium bis(trifluoromethanesulfonyl)imide ([P2225][Tf2N]) and (2-methoxyethyl)trimethylphosphonium bis(trifluoromethanesulfonyl)imide ([P222(201)][Tf2N]), and their mixtures with Li(+). Properties such as the electrochemical window, density, viscosity and ionic conductivity are presented.
Xianyin Lai et al.
Cancer genomics & proteomics, 12(6), 271-281 (2015-11-07)
Follicular adenoma is a type of benign and encapsulated nodule in the thyroid gland, but some adenomas have the potential to progress to follicular carcinoma. Therefore, it is important to monitor the state and progress of follicular adenoma in the



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货号GTIN
346179-50ML04061826761014