346225
(2-甲基丙基)硼酸
≥95.0%
别名:
异丁基硼酸
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关于此项目
线性分子式:
(CH3)2CHCH2B(OH)2
化学文摘社编号:
分子量:
101.94
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Level
assay
≥95.0%
form
solid
mp
108-111 °C (lit.)
SMILES string
CC(C)CB(O)O
InChI
1S/C4H11BO2/c1-4(2)3-5(6)7/h4,6-7H,3H2,1-2H3
InChI key
ZAZPDOYUCVFPOI-UHFFFAOYSA-N
Application
（2-甲基丙基）硼酸可用作：
它还可用作以下反应的反应物：
- 通过与4-溴异喹啉的Suzuki-Miyaura偶联反应制备4-异丁基异喹啉的反应物。
- 与氢氧化铝和硼酸一起用作苯乙烯聚合的催化剂。
它还可用作以下反应的反应物：
- 铜催化的交叉偶联反应。
- 通过铱催化的C-H硼化反应合成聚硼基烷。
- 杂取代二氮杂硼杂环戊二烯和硼杂环化合物的制备。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Takeshi Yamamoto et al.
Organic letters, 21(16), 6235-6240 (2019-08-07)
Pyrazolylaniline serves as a temporary directing group attached to the boron atom of alkylboronic acids in Ir-catalyzed C(sp3)-H borylation. The reaction takes place at α-, β-, and γ-C-H bonds, giving polyborylated products including di-, tri-, tetra-, and even pentaborylalkanes. α-C-H
Solution-state 15N NMR and solid-state single-crystal XRD study of heterosubstituted diazaboroles and borinines prepared via an effective and simple microwave-assisted solvent-free synthesis
Slabber CA, et al.
Journal of Organometallic Chemistry, 723, 122-128 (2013)
Benjamin M Reeves et al.
Angewandte Chemie (International ed. in English), 58(44), 15697-15701 (2019-09-06)
A transition-metal-free reductive hydroxymethylation reaction has been developed, enabling the preparation of tetrahydroisoquinolines bearing C4-quaternary centers from the corresponding isoquinolines. Deuterium labelling studies and control experiments enable a potential mechanism to be elucidated which features a key Cannizzaro-type reduction followed
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 346225-5G | 04061826761045 |
| 346225-1G | 04061826136102 |