346713
(1S,2S)-(+)-1,2-环己二胺
98%
别名:
(1S)-反式-1,2-二氨基环己烷, (1S)-反式-1,2-环己二胺
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关于此项目
线性分子式:
C6H10(NH2)2
化学文摘社编号:
分子量:
114.19
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2801645
产品名称
(1S,2S)-(+)-1,2-环己二胺, 98%
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m0/s1
SMILES string
N[C@H]1CCCC[C@@H]1N
InChI key
SSJXIUAHEKJCMH-WDSKDSINSA-N
assay
98%
form
solid
optical activity
[α]20/D +25°, c = 5 in 1 M HCl
optical purity
ee: 99% (GLC)
bp
104-110 °C/40 mmHg (lit.)
mp
40-43 °C (lit.)
Quality Level
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Application
用于形成金属络合物的多功能配体。用于合成在不对称催化中具有应用潜力的手性 tropocoronand。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
158.0 °F - closed cup
flash_point_c
70 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Design principles of chiral carbon nanodots help convey chirality from molecular to nanoscale level.
Luka Ðorđević et al.
Nature communications, 9(1), 3442-3442 (2018-08-26)
The chirality of (nano)structures is paramount in many phenomena, including biological processes, self-assembly, enantioselective reactions, and light or electron spin polarization. In the quest for new chiral materials, metallo-organic hybrids have been attractive candidates for exploiting the aforementioned scientific fields.
Mukaiyama, T.
Aldrichimica Acta, 29, 59-59 (1996)
Chenier, P.J. et al.
Tetrahedron Letters, 38, 7341-7341 (1997)
Hidekazu Yamada et al.
Journal of the American Chemical Society, 134(17), 7250-7253 (2012-04-18)
Optically active amidine dimer strands having a variety of chiral and achiral linkers with different stereostructures are synthesized and used as templates for diastereoselective imine-bond formations between two achiral carboxylic acid monomers bearing a terminal aldehyde group and racemic 1,2-cyclohexanediamine
Ran Feng et al.
Dalton transactions (Cambridge, England : 2003), 42(6), 2130-2145 (2012-11-29)
In this paper, the origins of enantioselectivity in asymmetric ketone hydrogenation catalyzed by RuH(2)(binap)(cydn) (cydn = trans-1,2-diaminocyclohexane) were discussed. Fifteen substrates involving aromatic, heteroaromatic, olefinic and dialkyl prochiral ketones were used to probe the catalytic mechanism and find an effective
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