348325
三氯化硼 溶液
1.0 M in heptane
别名:
Boron chloride, Trichloroborane
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关于此项目
经验公式（希尔记法）:
BCl3
化学文摘社编号:
分子量:
117.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
Application
- 三氯化硼，一种路易斯酸，是用于裂解各种醚和缩醛保护基团的常规试剂。
- 它是将芳族醛直接转化为相应的二氯化宝石的有用试剂。
- 它还可以与较少亲核试剂（例如锡和锆有机金属化合物）一起用于金属转移反应，合成各种有机硼烷。
用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
Packaging
推荐将25毫升安全/密封™瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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Danger
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
35.6 °F - closed cup
flash_point_c
2 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Migration of 1-alkenyl groups from zirconium to boron compounds.
Cole T E, et al.
Organometallics, 10(10), 3777-3781 (1991)
Boron Trichloride
Miyaura N, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2006)
Impact of Different Environmental Stimuli on the Release of 1-MCP from Boron-MCP Complexes.
Shahrin T, et al.
Journal of Plant Studies, 6(1), 46-46 (2016)
Conversion of aromatic aldehydes to gem-dichlorides using boron trichloride. A new highly efficient method for preparing dichloroarylmethanes.
Kabalka G W and Wu Z
Tetrahedron Letters, 41(5), 579-581 (2000)
Warwick J Belcher et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 1602-1614 (2008-03-13)
The reactions of boron halides with free base porphyrins under conditions where partial hydrolysis of the boron halides can occur give diboron porphyrin complexes containing BOB moieties in which each boron is bonded to two porphyrin nitrogen atoms. BF(3).OEt(2) with
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