35820
二氯乙酸乙酯
≥99.0% (GC)
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关于此项目
线性分子式:
Cl2CHCOOC2H5
化学文摘社编号:
分子量:
157.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-611-6
Beilstein/REAXYS Number:
773995
MDL number:
Assay:
≥99.0% (GC)
InChI key
IWYBVQLPTCMVFO-UHFFFAOYSA-N
InChI
1S/C4H6Cl2O2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3
SMILES string
CCOC(=O)C(Cl)Cl
assay
≥99.0% (GC)
refractive index
n20/D 1.438
bp
54-55 °C/11 mmHg (lit.)
density
1.28 g/mL at 20 °C (lit.)
functional group
chloro, ester
Quality Level
General description
二氯乙酸乙酯是一种酯，据报道其碱催化水解。
Application
二氯乙酸乙酯可用于α-卤代羧酸酯的合成。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Reaction of B-alkyl-9-borabicyclo [3.3. 1] nonanes with ethyl mono-and dihaloacetates under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters or. alpha.-halo esters via hydroboration.
Brown HC and Milorad M. Rogic.
Journal of the American Chemical Society, 91(8), 2146-2147 (1969)
General Base Catalysis of Ester Hydrolysis1.
Jencks WP and Carriuolo J.
Journal of the American Chemical Society, 83(7), 1743-1750 (1961)
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