35820
二氯乙酸乙酯
≥99.0% (GC)
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关于此项目
线性分子式:
Cl2CHCOOC2H5
化学文摘社编号:
分子量:
157.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-611-6
Beilstein/REAXYS Number:
773995
MDL number:
Assay:
≥99.0% (GC)
InChI key
IWYBVQLPTCMVFO-UHFFFAOYSA-N
InChI
1S/C4H6Cl2O2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3
SMILES string
CCOC(=O)C(Cl)Cl
assay
≥99.0% (GC)
refractive index
n20/D 1.438
bp
54-55 °C/11 mmHg (lit.)
density
1.28 g/mL at 20 °C (lit.)
functional group
chloro, ester
Quality Level
General description
二氯乙酸乙酯是一种酯，据报道其碱催化水解。
Application
二氯乙酸乙酯可用于α-卤代羧酸酯的合成。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
General Base Catalysis of Ester Hydrolysis1.
Jencks WP and Carriuolo J.
Journal of the American Chemical Society, 83(7), 1743-1750 (1961)
Reaction of B-alkyl-9-borabicyclo [3.3. 1] nonanes with ethyl mono-and dihaloacetates under the influence of potassium tert-butoxide. A convenient procedure for the conversion of olefins into esters or. alpha.-halo esters via hydroboration.
Brown HC and Milorad M. Rogic.
Journal of the American Chemical Society, 91(8), 2146-2147 (1969)
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