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359378

N-异丙基甲胺

Name: <I>N</I>-异丙基甲胺
Brand: ALDRICH

98%

别名:

N-甲基异丙胺

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关于此项目

线性分子式:

(CH₃)₂CHNHCH₃

化学文摘社编号:

4747-21-1

分子量:

73.14

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24862072

EC Number:

225-266-7

Beilstein/REAXYS Number:

1730877

MDL number:

MFCD00042859

Assay:

98%

Form:

liquid

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属性

vapor pressure

4.15 psi ( 20 °C)

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.384 (lit.)

bp

50-53 °C (lit.)

density

0.702 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CNC(C)C

InChI

1S/C4H11N/c1-4(2)5-3/h4-5H,1-3H3

InChI key

XHFGWHUWQXTGAT-UHFFFAOYSA-N

说明

General description

N-异丙基甲基胺是一种不对称胺。Pd/C催化的N-异丙基甲胺与醇的氧化交叉双羰基化已被报道。

Application

N-异丙基甲胺适用于通过由可逆加成-断裂链转移（RAFT）聚合反应而制备的一系列刺激响应性两亲嵌段共聚物的顺序自组装而生成具有不同尺寸的原位胶束。它也适合用于按照Speeter和Anthony过程合成新型5-乙氧基-N,N-二烷基-[α,α,β,β-H₄]-色胺及其[α,α,β,β,β−D₄]-配对物。

pictograms

GHS02,GHS06,GHS05

signalword

Danger

hcodes

H225,H300,H314,H331

pcodes

P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

存储类别

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-25.6 °F - closed cup

flash_point_c

-32 °C - closed cup

ppe

Faceshields, Gloves, Goggles

法规信息

危险化学品

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MULTIMODAL HIERARCHICAL ?FRACTAL-LIKE? MICELLAR SOLUTIONS OF THERMO-RESPONSIVE DOUBLE-HYDROPHILIC ACRYLAMIDE BLOCK COPOLYMERS SYNTHESIZED BY RAFT POLYMERIZATION.

Amado E, et al.

Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 52(2), 691-692 (2011)

Pd/C-catalyzed synthesis of oxamates by oxidative cross double carbonylation of amines and alcohols under co-catalyst, base, dehydrating agent, and ligand-free conditions.

Sandip T Gadge et al.

The Journal of organic chemistry, 78(13), 6793-6797 (2013-06-06)

This work reports a mild, efficient, and ligand-free Pd/C-catalyzed protocol for the oxidative cross double carbonylation of amines and alcohols. Notably, the reaction does not requires any base, co-catalyst, dehydrating agent, or ligand. Pd/C solves the problem of catalyst recovery

Microwave-accelerated preparation and analytical characterization of 5-ethoxy-N,N-dialkyl-[α,α,β,β-H(4) ]- and [α,α,β,β-D(4) ]-tryptamines.

Ruchanok Tearavarich et al.

Drug testing and analysis, 3(9), 597-608 (2011-10-01)

The increased interest in N,N-dialkyl tryptamines is a reflection of their diverse range of biologically active properties. Deuterated derivatives are of interest for use as internal standards in bioanalytical or pharmacological assays. The present study reports on the synthesis of

全球贸易项目编号

货号	GTIN
359378-5ML	04061836826536
359378-10ML	04061831813234
359378-50ML	04061836826529