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关于此项目
经验公式(希尔记法):
C8H15N3
化学文摘社编号:
分子量:
153.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
281-791-1
Beilstein/REAXYS Number:
7635759
MDL number:
Assay:
98%
Form:
liquid
assay
98%
form
liquid
refractive index
n20/D 1.537 (lit.)
bp
75-79 °C/0.1 mmHg (lit.)
density
1.067 g/mL at 25 °C (lit.)
SMILES string
CN1CCCN2CCCN=C12
InChI
1S/C8H15N3/c1-10-5-3-7-11-6-2-4-9-8(10)11/h2-7H2,1H3
InChI key
OEBXWWBYZJNKRK-UHFFFAOYSA-N
General description
7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯是一种可溶性胺碱。 它与4-硝基苯基[双(二乙基磺酰基)]甲烷和苯基[双(二乙基磺酰基)]甲烷形成1:1配合物,并且已通过FT-IR、1H NMR和PM5半经验方法研究了它们的结构。 已经研究了7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯对菜籽油与甲醇的酯交换反应的催化性能。
Application
7-甲基-1,5,7-三氮杂二环[4.4.0]癸-5-烯可用于微波促进的、钯催化的与芳基/杂芳基九氟磺酸盐和胺的C-N键形成反应。 它可以作为强碱,用于研究多足配体溶剂、三(氧杂烷基)苯基硅烷和三(氧杂烷基)磷酸酯。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
商品
The prevalence of organofluorine compounds in industry and drug design necessitates the ability to introduce C–F bonds to molecules.
Spectroscopic studies of the 1: 1 complexes of 4-nitrophenyl [bis (ethylsulfonyl)] methane and phenyl [bis (ethylsulfonyl)] methane with 7-methyl-1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene and 1, 5, 7-triazabicyclo [4.4. 0] dec-5-ene.
Huczynski A, et al.
Journal of Molecular Structure, 841(1), 133-136 (2007)
Rachel E Tundel et al.
The Journal of organic chemistry, 71(1), 430-433 (2006-01-04)
[reaction: see text] Microwave-assisted, palladium-catalyzed C-N bond-forming reactions with aryl/heteroaryl nonaflates and amines using the soluble amine bases DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) or MTBD (7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene) and ligands (1-3) resulted in good to excellent yields (71-99%) of arylamines in short reaction times (1-45
Transesterification of vegetable oils: a review.
Schuchardt U, et al.
Journal of the Brazilian Chemical Society, 9(3), 199-210 (1998)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 359505-1ML | 04061838053848 |
| 359505-5ML | 04061831813272 |
