359939
( R )-(+)-冰片胺
97%
别名:
(+)-降冰片胺, 内型-(1R)-1,7,7-三甲基二环[2.2.1]庚-2-胺
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关于此项目
经验公式（希尔记法）:
C10H19N
化学文摘社编号:
分子量:
153.26
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-076-9
Beilstein/REAXYS Number:
2801831
MDL number:
Assay:
97%
InChI key
MDFWXZBEVCOVIO-WEDXCCLWSA-N
InChI
1S/C10H19N/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7-8H,4-6,11H2,1-3H3/t7-,8+,10+/m1/s1
SMILES string
CC1(C)[C@@H]2CC[C@@]1(C)[C@@H](N)C2
assay
97%
optical activity
[α]20/D +44°, c = 0.5 in ethanol
mp
160-163 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
(R)-(+)-Bornylamine in the presence of acetonitrile as a solvent and tetraethylammonium bromide as the bromide ion source, may be used in the crystallization-induced chiral inversion of (S)-2-bromo-3-phenylpropanoic acid to its (R)-enantiomer. It may also be used to synthesize trans-bis{(R)-(+)-bornylamino}palladium(II) dichloride, a palladium(II) complex with potent antitumor activity.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Crystallization-Induced Chiral Inversion As the Key Step for Synthesis of (S)-2-Acetylthio-3-phenylpropanoic Acid from l-Phenylalanine.
Chen JG, et al.
Organic Letters, 6(19), 3233-3235 (2004)
Synthesis, crystal structure and initial biological evaluation of the new enantiomerically pure chiral palladium (II) complex trans-bis {endo-(1R)-1, 7, 7-trimethylbicyclo [2.2. 1]-heptan-2-amino} palladium (II) dichloride.
Abu-Surrah AS, et al.
European Journal of Medicinal Chemistry, 37(11), 919-922 (2002)
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